Concentration effects in homopolymerization of amine- and amide-containing (meth)acrylic monomers in organic solvents

Concentration effects in homopolymerization of amine- and amide-containing (meth)acrylic monomers... The dependences of the initial reduced rate of radical homopolymerization on the initial concentration of the monomers were studied for toluene and dimethylformamide solutions of four amine-containing (meth)acrylic esters and amides, and also for N-(n-butyl)acrylamide and n-butyl methacrylate taken for comparison. The concentration effects are similar for all the methacrylic monomers and are specific in the case of acrylamides {N-(n-butyl)acrylamide and N-[3-(dimethylamino)propyl]acrylamide}, which is associated with the specific features of the structure of the prereaction monomeric associates. Russian Journal of Applied Chemistry Springer Journals

Concentration effects in homopolymerization of amine- and amide-containing (meth)acrylic monomers in organic solvents

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Pleiades Publishing
Copyright © 2015 by Pleiades Publishing, Ltd.
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
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