Complexes of Cu(II) and Co(II) nitrates with 3-Phenyl-5,5-dimethyl-5,6-dihydro-1,2,4-triazolo[3,4-a]isoquinoline

Complexes of Cu(II) and Co(II) nitrates with... Complexes of Cu(II) and Co(II) nitrates with 3-phenyl-5,5-dimethyl-5,6-dihydro-1,2,4-triazolo[3,4-a]isoquinoline (L0) of the composition [CuL 2 0 (NO3)2] (I) and [CoL 2 0 (NO3)2] · CH3CN (II) are synthesized and their crystal structures are determined by X-ray diffraction. The L0 ligand is coordinated to the metal atoms through the N atom in position 2 of triazole fragment. The coordination polyhedron of the Cu(II) atom is a square with two additional axial vertices, while that of the Co(II) atom is a tetrahedron with two additional vertices. The NO 3 − groups in the structures of I and II perform similar anisobidentate function. Complexes I and II are studied by IR and electronic spectroscopy. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Complexes of Cu(II) and Co(II) nitrates with 3-Phenyl-5,5-dimethyl-5,6-dihydro-1,2,4-triazolo[3,4-a]isoquinoline

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328406060030
Publisher site
See Article on Publisher Site

Abstract

Complexes of Cu(II) and Co(II) nitrates with 3-phenyl-5,5-dimethyl-5,6-dihydro-1,2,4-triazolo[3,4-a]isoquinoline (L0) of the composition [CuL 2 0 (NO3)2] (I) and [CoL 2 0 (NO3)2] · CH3CN (II) are synthesized and their crystal structures are determined by X-ray diffraction. The L0 ligand is coordinated to the metal atoms through the N atom in position 2 of triazole fragment. The coordination polyhedron of the Cu(II) atom is a square with two additional axial vertices, while that of the Co(II) atom is a tetrahedron with two additional vertices. The NO 3 − groups in the structures of I and II perform similar anisobidentate function. Complexes I and II are studied by IR and electronic spectroscopy.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Jun 15, 2006

References

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