Complexes of Copper(I) with Dimercapto Compounds as Catalysts for Oxidation of Mercaptans and Hydrogen Sulfide with Molecular Oxygen in Aqueous Solutions

Complexes of Copper(I) with Dimercapto Compounds as Catalysts for Oxidation of Mercaptans and... The conditions for formation of complexes of copper(I) with mercapto compounds in aqueous- alkaline solutions and the catalytic activity of these complexes in oxidation of mercaptans and hydrogen sulfide was studied. The kinetic characteristics of these catalysts were compared with those of catalysts based on cobalt phthalocyanines. A method was proposed for suppressing formation of the thiosulfate ion in oxidation of H2S to elemental sulfur. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Complexes of Copper(I) with Dimercapto Compounds as Catalysts for Oxidation of Mercaptans and Hydrogen Sulfide with Molecular Oxygen in Aqueous Solutions

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Publisher
Kluwer Academic Publishers-Plenum Publishers
Copyright
Copyright © 2003 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1023/A:1023300101895
Publisher site
See Article on Publisher Site

Abstract

The conditions for formation of complexes of copper(I) with mercapto compounds in aqueous- alkaline solutions and the catalytic activity of these complexes in oxidation of mercaptans and hydrogen sulfide was studied. The kinetic characteristics of these catalysts were compared with those of catalysts based on cobalt phthalocyanines. A method was proposed for suppressing formation of the thiosulfate ion in oxidation of H2S to elemental sulfur.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Oct 4, 2004

References

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