Complexes {Cp*(Dppe)FeC≡CC2R[Co2L2(CO)4]} n+ (R = H, Si(CH3)3; n = 0, 1, 2; L2 = (CO)2, Dppm): Synthesis, redox properties, and electronic characteristics

Complexes {Cp*(Dppe)FeC≡CC2R[Co2L2(CO)4]} n+ (R = H, Si(CH3)3; n = 0, 1, 2; L2 = (CO)2, Dppm):... New neutral and cationic complexes containing the mononuclear organoiron Cp*(Dppe)Fe and cluster Co2C2 fragments have been synthesized. It was shown that the redox reactions substantially extend possibilities for the synthesis of the cationic complexes, and the transition metal derivatives with the unoccupied electron shell represent an interesting and promising direction of studies. It has been confirmed by spectroscopy in the near-IR range a substantial intramolecular electron interaction between the cobalt and iron atoms in the cationic complexes. The obtained estimates for the interaction energy suggest that these compounds can be perspective as molecular devices. Russian Journal of Coordination Chemistry Springer Journals

Complexes {Cp*(Dppe)FeC≡CC2R[Co2L2(CO)4]} n+ (R = H, Si(CH3)3; n = 0, 1, 2; L2 = (CO)2, Dppm): Synthesis, redox properties, and electronic characteristics

Loading next page...
Pleiades Publishing
Copyright © 2015 by Pleiades Publishing, Ltd.
Chemistry; Physical Chemistry; Inorganic Chemistry
Publisher site
See Article on Publisher Site


You’re reading a free preview. Subscribe to read the entire article.

DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

Monthly Plan

  • Read unlimited articles
  • Personalized recommendations
  • No expiration
  • Print 20 pages per month
  • 20% off on PDF purchases
  • Organize your research
  • Get updates on your journals and topic searches


Start Free Trial

14-day Free Trial

Best Deal — 39% off

Annual Plan

  • All the features of the Professional Plan, but for 39% off!
  • Billed annually
  • No expiration
  • For the normal price of 10 articles elsewhere, you get one full year of unlimited access to articles.



billed annually
Start Free Trial

14-day Free Trial