Comparison of photoinduced electron transfer reactions of C60 and aromatic carbonyl compounds

Comparison of photoinduced electron transfer reactions of C60 and aromatic carbonyl compounds The one-electron reduction potential of the triplet excited state of C60 is similar to those of some aromatic carbonyl compounds. Thus, photoinduced electron transfer is expected to occur from the common electron donors to both C60 and aromatic carbonyl compounds. In this paper comparison is made between photoinduced electron transfer from organosilanes and organostannanes used as the electron donors to the triplet excited states of C60 and aromatic carbonyl compounds, providing valuable insight into their common mechanistic features for the C-C bond formation via photoinduced electron transfer as well as the new functionalization method of C60. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Comparison of photoinduced electron transfer reactions of C60 and aromatic carbonyl compounds

Loading next page...
 
/lp/springer_journal/comparison-of-photoinduced-electron-transfer-reactions-of-c60-and-nQ7dKqUNDa
Publisher
Springer Netherlands
Copyright
Copyright © 1997 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856797X00213
Publisher site
See Article on Publisher Site

Abstract

The one-electron reduction potential of the triplet excited state of C60 is similar to those of some aromatic carbonyl compounds. Thus, photoinduced electron transfer is expected to occur from the common electron donors to both C60 and aromatic carbonyl compounds. In this paper comparison is made between photoinduced electron transfer from organosilanes and organostannanes used as the electron donors to the triplet excited states of C60 and aromatic carbonyl compounds, providing valuable insight into their common mechanistic features for the C-C bond formation via photoinduced electron transfer as well as the new functionalization method of C60.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 14, 2009

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve Freelancer

DeepDyve Pro

Price
FREE
$49/month

$360/year
Save searches from Google Scholar, PubMed
Create lists to organize your research
Export lists, citations
Access to DeepDyve database
Abstract access only
Unlimited access to over
18 million full-text articles
Print
20 pages/month
PDF Discount
20% off