Comparative study on thephysical properties of transition metal-doped (Co, Ni, Fe, and Mn) ZnO nanoparticles

Comparative study on thephysical properties of transition metal-doped (Co, Ni, Fe, and Mn) ZnO... Nano-crystalline of TM-doped ZnO with general formula Zn0.97TM0.03O (TM: Mn, Fe, Co, and Ni) was prepared using sol–gel method. The dependence of crystal structure, morphology, and optical and magnetic properties on the type of transition metals was investigated. The XRD investigation of pure and TM-doped ZnO nanoparticles samples confirms the formation of single-phase hexagonal wurtzite structure. The estimated crystallite sizes are found in the range of 17 and 38 nm for the doped and pure samples, respectively. The obtained data suggest that the dopant type plays a vital role in the physical properties of the investigated samples. The optical band-gap energy Eg has been calculated from near infrared (NIR) and visible (VIS) reflectance spectra using the Kubelka–Munk function. Minimum value of 2.398 eV and maximum one of 3.29 eV were obtained for Manganese-doped ZnO and pure ZnO, respectively. The analysis of XRD and VSM of the samples confirms that the observed room-temperature (RT) ferromagnetism can be attributed to an intrinsic property of doped material sample and not due to formation of any secondary phase. The magnetic results show that Mn is the most effective dopant for producing ferromagnetism in nanoparticles of ZnO. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Applied Physics A: Materials Science Processing Springer Journals

Comparative study on thephysical properties of transition metal-doped (Co, Ni, Fe, and Mn) ZnO nanoparticles

10 pages
Read Article

Loading next page...
 
/lp/springer_journal/comparative-study-on-thephysical-properties-of-transition-metal-doped-DXDuBgYwDv
Publisher
Springer Journals
Copyright
Copyright © 2018 by Springer-Verlag GmbH Germany, part of Springer Nature
Subject
Physics; Condensed Matter Physics; Optical and Electronic Materials; Nanotechnology; Characterization and Evaluation of Materials; Surfaces and Interfaces, Thin Films; Operating Procedures, Materials Treatment
ISSN
0947-8396
eISSN
1432-0630
D.O.I.
10.1007/s00339-018-1871-3
Publisher site
See Article on Publisher Site

Abstract

Nano-crystalline of TM-doped ZnO with general formula Zn0.97TM0.03O (TM: Mn, Fe, Co, and Ni) was prepared using sol–gel method. The dependence of crystal structure, morphology, and optical and magnetic properties on the type of transition metals was investigated. The XRD investigation of pure and TM-doped ZnO nanoparticles samples confirms the formation of single-phase hexagonal wurtzite structure. The estimated crystallite sizes are found in the range of 17 and 38 nm for the doped and pure samples, respectively. The obtained data suggest that the dopant type plays a vital role in the physical properties of the investigated samples. The optical band-gap energy Eg has been calculated from near infrared (NIR) and visible (VIS) reflectance spectra using the Kubelka–Munk function. Minimum value of 2.398 eV and maximum one of 3.29 eV were obtained for Manganese-doped ZnO and pure ZnO, respectively. The analysis of XRD and VSM of the samples confirms that the observed room-temperature (RT) ferromagnetism can be attributed to an intrinsic property of doped material sample and not due to formation of any secondary phase. The magnetic results show that Mn is the most effective dopant for producing ferromagnetism in nanoparticles of ZnO.

Journal

Applied Physics A: Materials Science Processing – Springer Journals

Published: Jun 2, 2018

References

  • New materials for spintronics
    Chambers, SA; Yoo, YK
  • Origin, development, and future of spintronics (Nobel lecture)
    Fert, A
  • REview: device physics
    Prinz, GA
  • Review of zinc oxide (ZnO) nanoparticles applications and properties
    Uikey, P; Vishwakarma, K
  • Synthesis and physical properties of Mn doped ZnO dilute magnetic semiconductor nanostructures
    Iqbal, J; Liu, X; Majid, A; Yu, R
  • Thin-film transistor fabricated in single-crystalline transparent oxide semiconductor
    Nomura, K; Ohta, H; Ueda, K; Kamiya, T; Hirano, M; Hosono, H
  • Improved zinc oxide film for gas sensor applications
    Roy, S; Basu, S
  • Direct synthesis of highly crystalline transparent conducting oxide nanoparticles by low pressure spray pyrolysis
    Ogi, T; Hidayat, D; Iskandar, F; Purwanto, A; Okuyama, K
  • Zinc oxide nanoparticles: a promising nanomaterial for biomedical applications
    Mishra, PK; Mishra, H; Ekielski, A; Talegaonkar, S; Vaidya, B
  • Piezoelectric characterization individual zinc oxide nanobelt probed by piezoresponse force microscope
    Zhao, MH; Wang, ZL; Mao, SX
  • Oxygen vacancy-induced ferromagnetism in un-doped ZnO thin films
    Zhan, P; Wang, W; Liu, C; Hu, Y; Li, Z; Zhang, Z; Zhang, P; Wang, B; Cao, X
  • Defects induced room temperature ferromagnetism in ZnO thin films
    Zhang, X; Zhang, W; Zhang, X; Xu, X; Meng, F; Tang, CC
  • Effect of annealing atmosphere on magnetic properties of pure ZnO and Na: ZnO films
    Wu, K; Xu, X; Yang, H; Zhang, J; Miao, J; Jiang, Y
  • Ferromagnetism of Zinc Oxide Nanograined Films
    Straumal, BB; Protasova, SG; Mazilkin, AA; Goering, E; Baretzky, B; Straumal, PB
  • Ferromagnetic transition metal implanted ZnO: A diluted magnetic semiconductor?
    Zhou, S; Potzger, K; Xu, Q; Talut, G; Lorenz, M; Skorupa, W; Helm, M; Fassbender, J; Grundmann, M; Schmidt, H
  • Temperature dependence of solubility limits of transition metals (Co, Mn, Fe, and Ni) in ZnO nanoparticles
    Mandal, SK; Das, AK; Nath, TK; Karmakar, D
  • Analysis of X-ray diffraction patterns from mechanically alloyed Al-Ti powders
    Hye-Sung, KIM; Dong-Soo, SUHR; Gyeung-Ho, KIM; Dong-Wha, KUM
  • Limit of detection in X-ray diffraction measurements of tissue equivalent samples
    Vassiljev, NL; Konstantinidis, A; Griffiths, J; Speller, R
  • Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
    Shannon, RD
  • Zinc oxide nanostructures: growth
    Wang, ZL
  • Lattice constant of doped semiconductor
    Leszczyński, Μ; Suski, T
  • The effects of heat treatment on room temperature ferromagnetism in a digitally Co doped ZnO thin film
    Kang, S; Kim, Y; Kim, SE; Kim, S
  • X-ray analysis of Fe doped ZnO Nanoparticles by Williamson-Hall and Size-Strain Plot
    Prabhu, YT; Venkateswara Methods Rao, K; Sesha Sai Kumar, V; Siva Kumari, B
  • X-ray analysis by Williamson-Hall and size-strain plot methods of ZnO nanoparticles with fuel variation
    Prabhu, YT; Rao, KV
  • Effect of cobalt doping on structural, optical, and magnetic properties of ZnO nanoparticles synthesized by coprecipitation method
    Gandhi, V; Ganesan, R; Hameed, H; Syedahamed, A; Thaiyan, M
  • Optical properties of ZnO nanoparticles
    Bose, SSML; Kc, G
  • Effects of annealing temperature on some structural and optical properties of ZnO nanoparticles prepared by a modified sol-gel combustion method
    Zak, AK; Abrishami, ME; Majid, WHA; Yousefi, R; Hosseini, SM
  • Results in physics influence of Mn doping on the magnetic and optical properties of ZnO nanocrystalline particles
    Shatnawi, M; Alsmadi, AM; Bsoul, I; Salameh, B; Mathai, M; Alnawashi, G; Alzoubi, GM; Al-dweri, F; Bawa, MS
  • Optical and electronic properties of some binary semiconductors from energy gaps
    Tripathy, SK; Pattanaik, A
  • Effects of Cr-doping on the optical and magnetic properties in ZnO nanoparticles prepared by sol-gel method
    Liu, Y; Yang, J; Guan, Q; Yang, L; Zhang, Y; Wang, Y; Feng, B; Cao, J; Liu, X; Yang, Y; Wei, M
  • The structural, electronic and magnetic properties of the 3d TM (V, Cr, Mn, Fe, Co, Ni and Cu) doped ZnO nanotubes: a first-principles study
    Jianmin, Z; Dan, GAO; Kewei, XU
  • Effect of transition metal (Co, Ni and Cu) doping on lattice volume, band gap, morphology and saturation magnetization of ZnO nanostructures
    Ahmed, F; Arshi, N; Anwar, MS; Danish, R; Koo, BH
  • Band gap engineering in ZnO By doping with 3d transition metal ions
    Joseph, DP; Venkateswaran, C
  • Direct relationship between lattice volume, bandgap, morphology and magnetization of transition metals (Cr, Mn and Fe) -doped ZnO nanostructures
    Ahmed, F; Kumar, S; Arshi, N; Anwar, MS; Heo, SN; Koo, BH
  • Synergistic effect of La and Co co-doping on room-temperature ferromagnetism enhancement of TiO2 nanoparticles
    Zhang, H; Ouyang, X; Yang, B; Lutes, R; Ni, Y
  • Ferromagnetism in Cr-, Fe-, and Ni-doped TiO2 samples
    Ahmed, SA
  • Correlation between saturation magnetization, bandgap, and lattice volume of transition metal, M=Cr, Mn, Fe, Co, or Ni doped Zn1–x Mx O nanoparticles
    Anghel, J; Thurber, A; Tenne, DA; Hanna, CB; Punnoose, A
  • Interactions in multilayer magnetic films, physics of thin films
  • Positive exchange bias in Fe F2 -Fe bilayers
    Nogués, J; Lederman, D; Moran, TJ; Schuller, IK
  • Increased exchange anisotropy due to disorder at permalloy/CoO interfaces
    Moran, TJ; Gallego, JM; Schuller, IK
  • Exchange Anisotropy and Strain Interactions in the Ni-NiO System
    Berkowitz, AE; Greiner, JH
  • Fine particles, thin films and exchange anisotropy
    Jacobs, IS; Bean, CP
  • A ferromagnetic-antiferromagnetic model for copper-manganese and related alloys
    Kouvel, J
  • Tailoring magnetic properties of core∕shell nanoparticles
    Zeng, H; Sun, S; Li, J; Wang, ZL; Liu, JP
  • Acicular gamma -Fe/sub 2/O/sub 3/ particles surface-coated with barium ferrite
    Deng, M; Hsu, S; Chin, T
  • Coercive field enhancement of rare-earth-coated Fe4N nitride particles
    Matar, S; Siberchicot, B; Demazeau, G; Berthon, S
  • Low Temperature Surface Spin-Glass Transition in γ- Fe2O3 Nanoparticles
    Martinez, B; Obradors, X; Balcells, L; Rouanet, A; Monty, C
  • Surface spin disorder in NiFe2O4 nanoparticles
    Kodama, RH; Berkowitz, AE; McNiff, JEJ; Foner, S
  • Electron paramagnetic resonance spectra near the spin-glass transition in iron oxide nanoparticles
    Koksharov, Y; Gubin, S; Kosobudsky, I; Yurkov, GY; Pankratov, D; Ponomarenko, L; Mikheev, M; Beltran, M; Khodorkovsky, Y; Tishin, A
  • Exchange bias in Bi Fe0.8Mn0.2O3 nanoparticles with an antiferromagnetic core and a diluted antiferromagnetic shell
    Manna, PK; Yusuf, SM; Shukla, R; Tyagi, AK
  • Coexistence of sign reversal of both magnetization and exchange bias field in the core-shell type La0.2Ce0.8CrO3 La0.2Ce0.8CrO3 nanoparticles
    Manna, PK; Yusuf, SM; Shukla, R; Tyagi, AK
  • Structural, magnetic and electrical properties of Bi doped LaFeO3 nano-crystals, synthesized by auto-combustion method
    Ahmed, MA; Azab, AA; El-Khawas, EH
  • Unusual features of ferromagnetic/antiferromagnetic nanocomposites
    Azab, AA; El-Dek, SI; Solyman, S
  • Temperature dependent magnetic properties of Co1+xTxFe2–2xO4(T=Zr, Ti)
    Monaji, VR; Indla, S; Rayaprol, S; Sowmya, S; Srinivas, A; Das, D
  • Origin of the magnetic anisotropy energy of cobalt ferrite
    Tachiki, M
  • Influence of thermal treatments on phase formation and magnetic behaviour in metal transition doped TiO2
    Cabrera, AF; Errico, L; Rodríguez Torres, CE; Sánchez, FH

You’re reading a free preview. Subscribe to read the entire article.

Try 2 weeks free now

DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

or browse the journals available

Search

Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly

Organize

Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.

Access

Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve

Freelancer

DeepDyve

Pro

Price

FREE

$49/month
$360/year

Save searches from
Google Scholar,
PubMed

Create folders to
organize your research

Export folders, citations

Read DeepDyve articles

Abstract access only

Unlimited access to over
18 million full-text articles

Print

20 pages / month

PDF Discount

20% off

Sign up
for free
Start 14 day
Free Trial