Combined neutralization of nitrogen(I), (II), and (IV) oxides in production of adipic acid

Combined neutralization of nitrogen(I), (II), and (IV) oxides in production of adipic acid Compositions of a catalyst and a chemisorbent for effective purification of oxygen-containing effluent gases in production of adipic acid to remove N2O, NO, and NO2 were developed. Their use enables catalytic decomposition of N2O as the prevalent component at temperatures of up to 500°C and chemisorption purification to remove microimpurities of NO and NO2 at 20°C and in excess amount of oxygen. The optimization of the catalyst and chemisorbent compositions made it possible to diminish the content of the expensive ruthenium and cerium to 4.5 and 4.2 wt %, respectively, with the developed service characteristics preserved. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Combined neutralization of nitrogen(I), (II), and (IV) oxides in production of adipic acid

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427215090013
Publisher site
See Article on Publisher Site

Abstract

Compositions of a catalyst and a chemisorbent for effective purification of oxygen-containing effluent gases in production of adipic acid to remove N2O, NO, and NO2 were developed. Their use enables catalytic decomposition of N2O as the prevalent component at temperatures of up to 500°C and chemisorption purification to remove microimpurities of NO and NO2 at 20°C and in excess amount of oxygen. The optimization of the catalyst and chemisorbent compositions made it possible to diminish the content of the expensive ruthenium and cerium to 4.5 and 4.2 wt %, respectively, with the developed service characteristics preserved.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Dec 23, 2015

References

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