Co3O4 nanoparticles prepared by oxidative precipitation method: an efficient and reusable heterogeneous catalyst for N-formylation of amines

Co3O4 nanoparticles prepared by oxidative precipitation method: an efficient and reusable... NH 2 NHCHO NH NHCHO CH 3 CH Co O Nanoparticles 3 4 Cl Cl NHCHO NHCHO NH NH 2 2 OHCHN H N Keywords Amines  Co O nanoparticles  Formic acid  N-formylation 3 4 Heterogeneous catalyst & Ahmad Poursattar Marjani a.poursattar@gmail.com; a.poursattar@urmia.ac.ir Department of Chemistry, Faculty of Science, Urmia University, Urmia 57154, Iran 123 414 A. P. Marjani et al. Introduction The formyl group is one of the most important groups for the protection of amines [1]. Formamides, the corresponding products, are important intermediates which have been widely applied in the synthesis of fine chemicals [2, 3] and pharmaceutically important compounds such as fluoroquinolines [4], imidazoles [2], 1,2-dihydroquinolines [5], nitrogen-bridged heterocycles [6], oxazolidinones [7], and cancer chemotherapeutic agents [8]. Also, formamides are applied as catalysts in the allylation [9], hydrosilylation [10] and reaction of carbonyl compounds. They are used as reagents in Vilsmeier formylation [11] and in the synthesis of formamidines and isocyanides [12]. A large number of methods have been reported for the N-formylation of amines [13–22], but most of them suffer from major drawbacks such as thermal instability, sensitivity to moisture, application of toxic and expensive formylating agents and catalysts, high temperatures, prolonged reaction http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Co3O4 nanoparticles prepared by oxidative precipitation method: an efficient and reusable heterogeneous catalyst for N-formylation of amines

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Publisher
Springer Netherlands
Copyright
Copyright © 2016 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-016-2631-7
Publisher site
See Article on Publisher Site

Abstract

NH 2 NHCHO NH NHCHO CH 3 CH Co O Nanoparticles 3 4 Cl Cl NHCHO NHCHO NH NH 2 2 OHCHN H N Keywords Amines  Co O nanoparticles  Formic acid  N-formylation 3 4 Heterogeneous catalyst & Ahmad Poursattar Marjani a.poursattar@gmail.com; a.poursattar@urmia.ac.ir Department of Chemistry, Faculty of Science, Urmia University, Urmia 57154, Iran 123 414 A. P. Marjani et al. Introduction The formyl group is one of the most important groups for the protection of amines [1]. Formamides, the corresponding products, are important intermediates which have been widely applied in the synthesis of fine chemicals [2, 3] and pharmaceutically important compounds such as fluoroquinolines [4], imidazoles [2], 1,2-dihydroquinolines [5], nitrogen-bridged heterocycles [6], oxazolidinones [7], and cancer chemotherapeutic agents [8]. Also, formamides are applied as catalysts in the allylation [9], hydrosilylation [10] and reaction of carbonyl compounds. They are used as reagents in Vilsmeier formylation [11] and in the synthesis of formamidines and isocyanides [12]. A large number of methods have been reported for the N-formylation of amines [13–22], but most of them suffer from major drawbacks such as thermal instability, sensitivity to moisture, application of toxic and expensive formylating agents and catalysts, high temperatures, prolonged reaction

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Jul 12, 2016

References

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