NH 2 NHCHO NH NHCHO CH 3 CH Co O Nanoparticles 3 4 Cl Cl NHCHO NHCHO NH NH 2 2 OHCHN H N Keywords Amines Co O nanoparticles Formic acid N-formylation 3 4 Heterogeneous catalyst & Ahmad Poursattar Marjani email@example.com; firstname.lastname@example.org Department of Chemistry, Faculty of Science, Urmia University, Urmia 57154, Iran 123 414 A. P. Marjani et al. Introduction The formyl group is one of the most important groups for the protection of amines . Formamides, the corresponding products, are important intermediates which have been widely applied in the synthesis of ﬁne chemicals [2, 3] and pharmaceutically important compounds such as ﬂuoroquinolines , imidazoles , 1,2-dihydroquinolines , nitrogen-bridged heterocycles , oxazolidinones , and cancer chemotherapeutic agents . Also, formamides are applied as catalysts in the allylation , hydrosilylation  and reaction of carbonyl compounds. They are used as reagents in Vilsmeier formylation  and in the synthesis of formamidines and isocyanides . A large number of methods have been reported for the N-formylation of amines [13–22], but most of them suffer from major drawbacks such as thermal instability, sensitivity to moisture, application of toxic and expensive formylating agents and catalysts, high temperatures, prolonged reaction
Research on Chemical Intermediates – Springer Journals
Published: Jul 12, 2016
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