CO2-fixation into organic carbonyl compounds in visible-light-induced photocatalysis of linear aromatic compounds

CO2-fixation into organic carbonyl compounds in visible-light-induced photocatalysis of linear... CO2 is fixed into benzophenone using poly(p-phenylene) as a photocatalyst and triethylamine as an electron donor under visible light irradiation. The reaction was enhanced by the addition of onium cation with soft character. The enhanced formation of the radical anion and the dianion species in poly(p-phenylene) by sodium reduction was confirmed by the cation addition. The role of the anion species formed in the photocatalytic system is discussed as the electron pool for the photofixation. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

CO2-fixation into organic carbonyl compounds in visible-light-induced photocatalysis of linear aromatic compounds

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Publisher
Brill Academic Publishers
Copyright
Copyright © 2000 by VSP
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856700X00192
Publisher site
See Article on Publisher Site

Abstract

CO2 is fixed into benzophenone using poly(p-phenylene) as a photocatalyst and triethylamine as an electron donor under visible light irradiation. The reaction was enhanced by the addition of onium cation with soft character. The enhanced formation of the radical anion and the dianion species in poly(p-phenylene) by sodium reduction was confirmed by the cation addition. The role of the anion species formed in the photocatalytic system is discussed as the electron pool for the photofixation.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Jan 1, 2000

References

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