Cinnamaldehyde hydrogenation using ruthenium-tin catalyst type

Cinnamaldehyde hydrogenation using ruthenium-tin catalyst type Bimetallic ruthenium-tin catalysts were prepared using the sol-gel method and the method of carrier impregnation. Two different procedures were used for their reduction — reduction in hydrogen atmosphere under an increased temperature, and reduction using an aqueous solution of sodium borohydride. Hydrogenation of 3-phenylpropenal (cinnamaldehyde) in tetrahydrofuran at 433 K and the total pressure 7 MPa was used as the model reaction for comparing the catalytic properties of the prepared catalysts. It was demonstrated that a tin addition notably affected catalytic properties of ruthenium in the sense of a selectivity increment related to the production of an unsaturated alcohol. Research on Chemical Intermediates Springer Journals

Cinnamaldehyde hydrogenation using ruthenium-tin catalyst type

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Brill Academic Publishers
Copyright © 2000 by VSP
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
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