Chiral recognition and supramolecular photoreaction of 1,1′-binaphthol with bovine and human serum albumins

Chiral recognition and supramolecular photoreaction of 1,1′-binaphthol with bovine and human... In their pioneering study in 1991, Levi-Minzi and Zandomeneghi discovered that photoirradiation of racemic 1,1′-binaphthol (rac-1) in the presence of bovine serum albumin (BSA) in distilled water gave (R)-1 in 99 % enantiomeric excess (ee) after 77 % of the starting material had been consumed. No similar attempt was made with human serum albumin (HSA). In this study of the effects of phosphate buffer solution on the ground-state affinity and excited-state photobehavior of 1 with serum albumin we found that both BSA and HSA preferentially bind the (S) enantiomer of 1 and that photoreaction of rac-1 mediated by BSA and HSA affords (R)-1 in 98 % ee with 99 % conversion and in 46 % ee with 65 % conversion, respectively. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Chiral recognition and supramolecular photoreaction of 1,1′-binaphthol with bovine and human serum albumins

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Publisher
Springer Netherlands
Copyright
Copyright © 2012 by Springer Science+Business Media B.V.
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-012-0655-1
Publisher site
See Article on Publisher Site

References

  • Asymmetric photoreactions within zeolites: role of confinement and alkali metal ions
    Sivaguru, J; Natarajan, A; Kaanumalle, LS; Shailaja, J; Uppili, S; Joy, A; Ramamurthy, V
  • Highly enantioselective Diels-Alder reaction of a photochemically generated o-quinodimethane with olefins
    Grosch, B; Orlebar, CN; Herdtweck, E; Massa, W; Bach, T
  • Bio-supramolecular photochirogenesis with molecular chaperone: enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate mediated by prefoldin
    Bando, K; Zako, T; Sakono, M; Maeda, M; Wada, T; Nishijima, M; Fukuhara, G; Yang, C; Mori, T; Pace, TCS; Bohne, C; Inoue, Y

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