Chemistry of μ-η2:η2-peroxo dimetal complexes: A bioinorganic model triggers a new trend of transition metal peroxo species

Chemistry of μ-η2:η2-peroxo dimetal complexes: A bioinorganic model triggers a new trend of... Res. Chem. Intermed., Vol. 24, No. 3, pp. 291-307 (1998) 9 VSP 1998 CHEMISTRY OF ;x-~2:~-PEROXO DIMETAL COMPLEXES: A BIOINORGANIC MODEL TRIGGERS A NEW TREND OF TRANSITION METAL PEROXO SPECIES MUNETAKA AK1TA, KIYOSHI FUJISAWA, SHIRO HIKICHI AND YOSHIHIKO MORO-OKA* Research Laborato~ of Resources Utilization, Tokyo Institute of Technology, 4259 Nagatsuta, Midori- ku, Yokohama 226, Japan Received 16 October 1997; accepted 25 November 1997 CONTENTS I. Introduction g-rl2:rl2-peroxo Dicopper Complex as a Model for Oxidized II. Synthesis of Form of Hemocyanin Ili. Expansion of Chemistry of g-1]2:q2-peroxo Dimetal Species 1. Cobalt g-qz:q2-peroxo complex and related species 2. Nickel ~t-rl2:TI2-peroxo complex IV. Application to Catalytic Reactions 1. Reaction mechanism of tyrosinase 2. Regioselective dehydrogenative polymerization of phenol leading to poly(p-phenylene oxide) 3. Catalytic oxidation of hydrocarbons based on the TpRFe system V. Concluding Remarks VI. References I. INTRODUCTION The dioxygen molecule is the most abundant and cheapest oxidant, and many oxidative transformations of organic substrates are catalyzed by a transition metal species including both homogeneous and heterogeneous catalysts [1]. However, oxidation with dioxygen molecule is not always feasible, and much effort has been paid toward development of new (and, hopefully, catalytic) organic transformations. Needless to say, dioxygen molecule plays very important Research on Chemical Intermediates Springer Journals

Chemistry of μ-η2:η2-peroxo dimetal complexes: A bioinorganic model triggers a new trend of transition metal peroxo species

Loading next page...
Springer Netherlands
Copyright © 1998 by Springer
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
Publisher site
See Article on Publisher Site


You’re reading a free preview. Subscribe to read the entire article.

DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

Monthly Plan

  • Read unlimited articles
  • Personalized recommendations
  • No expiration
  • Print 20 pages per month
  • 20% off on PDF purchases
  • Organize your research
  • Get updates on your journals and topic searches


Start Free Trial

14-day Free Trial

Best Deal — 39% off

Annual Plan

  • All the features of the Professional Plan, but for 39% off!
  • Billed annually
  • No expiration
  • For the normal price of 10 articles elsewhere, you get one full year of unlimited access to articles.



billed annually
Start Free Trial

14-day Free Trial