Res. Chem. Intermed., Vol. 24, No. 3, pp. 291-307 (1998) 9 VSP 1998 CHEMISTRY OF ;x-~2:~-PEROXO DIMETAL COMPLEXES: A BIOINORGANIC MODEL TRIGGERS A NEW TREND OF TRANSITION METAL PEROXO SPECIES MUNETAKA AK1TA, KIYOSHI FUJISAWA, SHIRO HIKICHI AND YOSHIHIKO MORO-OKA* Research Laborato~ of Resources Utilization, Tokyo Institute of Technology, 4259 Nagatsuta, Midori- ku, Yokohama 226, Japan Received 16 October 1997; accepted 25 November 1997 CONTENTS I. Introduction g-rl2:rl2-peroxo Dicopper Complex as a Model for Oxidized II. Synthesis of Form of Hemocyanin Ili. Expansion of Chemistry of g-1]2:q2-peroxo Dimetal Species 1. Cobalt g-qz:q2-peroxo complex and related species 2. Nickel ~t-rl2:TI2-peroxo complex IV. Application to Catalytic Reactions 1. Reaction mechanism of tyrosinase 2. Regioselective dehydrogenative polymerization of phenol leading to poly(p-phenylene oxide) 3. Catalytic oxidation of hydrocarbons based on the TpRFe system V. Concluding Remarks VI. References I. INTRODUCTION The dioxygen molecule is the most abundant and cheapest oxidant, and many oxidative transformations of organic substrates are catalyzed by a transition metal species including both homogeneous and heterogeneous catalysts . However, oxidation with dioxygen molecule is not always feasible, and much effort has been paid toward development of new (and, hopefully, catalytic) organic transformations. Needless to say, dioxygen molecule plays very important
Research on Chemical Intermediates – Springer Journals
Published: Apr 15, 2009
It’s your single place to instantly
discover and read the research
that matters to you.
Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.
All for just $49/month
Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly
Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.
Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.
Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.
All the latest content is available, no embargo periods.
“Hi guys, I cannot tell you how much I love this resource. Incredible. I really believe you've hit the nail on the head with this site in regards to solving the research-purchase issue.”Daniel C.
“Whoa! It’s like Spotify but for academic articles.”@Phil_Robichaud
“I must say, @deepdyve is a fabulous solution to the independent researcher's problem of #access to #information.”@deepthiw
“My last article couldn't be possible without the platform @deepdyve that makes journal papers cheaper.”@JoseServera