Chemical and Electrochemical Synthesis, Structure, and Properties of Metal Chelates of Tridentate N,S-Containing Azomethinazo Ligands

Chemical and Electrochemical Synthesis, Structure, and Properties of Metal Chelates of Tridentate... Novel Cu(II), Co(II), Ni(II), and Zn(II) complexes of 5-methyl-2-phenyl-4-[(4-phenylazo)anilinemethylylidene]- 2,4-dihydro-3H-pyrazole-3-thione and 5-methyl-4-[4-methyl-2-(4-methylphenylazo)anilinemethylylidene]- 2-phenyl-2,4-dihydro-3H-pyrazole-3-thione, i.e. ligands containing the phenylazo group in the ortho and para positions of the aniline fragment, were synthesized by the chemical and electrochemical methods. The complexes and ligands were characterized by IR, 1H NMR, X-ray absorption spectroscopy and magnetochemistry. The azo group of the ligands is not involved in coordination to the metal. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of General Chemistry Springer Journals

Chemical and Electrochemical Synthesis, Structure, and Properties of Metal Chelates of Tridentate N,S-Containing Azomethinazo Ligands

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Publisher
Pleiades Publishing
Copyright
Copyright © 2018 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general
ISSN
1070-3632
eISSN
1608-3350
D.O.I.
10.1134/S1070363218020123
Publisher site
See Article on Publisher Site

Abstract

Novel Cu(II), Co(II), Ni(II), and Zn(II) complexes of 5-methyl-2-phenyl-4-[(4-phenylazo)anilinemethylylidene]- 2,4-dihydro-3H-pyrazole-3-thione and 5-methyl-4-[4-methyl-2-(4-methylphenylazo)anilinemethylylidene]- 2-phenyl-2,4-dihydro-3H-pyrazole-3-thione, i.e. ligands containing the phenylazo group in the ortho and para positions of the aniline fragment, were synthesized by the chemical and electrochemical methods. The complexes and ligands were characterized by IR, 1H NMR, X-ray absorption spectroscopy and magnetochemistry. The azo group of the ligands is not involved in coordination to the metal.

Journal

Russian Journal of General ChemistrySpringer Journals

Published: Mar 15, 2018

References

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