Chalcogenate-bridged heterometallic complexes containing tricarbonyl rhenium combined with cymene ruthenium

Chalcogenate-bridged heterometallic complexes containing tricarbonyl rhenium combined with cymene... The reaction of Re(CO)3(THF)2Cl with (Cymen)RuCl2 (Cymen = p-methyl-iso-propylbenzene) in benzene gave the known heterometallic complex (Cymen)Ru(μ-Cl)3Re(CO)3 (I), which was converted to the heterometallic complex (Cymen)Ru(μ-S-tert-Bu)3Re(CO)3 (II) on treatment with tert-butylmercaptan and triethylamine. Treatment of I with sodium tellurophenolate in THF results in the formation of the ionic complex [(Cymen)Ru(μ-TePh)3Ru(Cymen)]+[(CO)3Re(μ-TePh)3Re(CO)3]− (III) with homobinuclear cation and anion. The structures of II and III were determined by X-ray diffraction (CIF files CCDC nos. 1022559 (II) and 1022560 (III)). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Chalcogenate-bridged heterometallic complexes containing tricarbonyl rhenium combined with cymene ruthenium

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Publisher
Springer Journals
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415020074
Publisher site
See Article on Publisher Site

Abstract

The reaction of Re(CO)3(THF)2Cl with (Cymen)RuCl2 (Cymen = p-methyl-iso-propylbenzene) in benzene gave the known heterometallic complex (Cymen)Ru(μ-Cl)3Re(CO)3 (I), which was converted to the heterometallic complex (Cymen)Ru(μ-S-tert-Bu)3Re(CO)3 (II) on treatment with tert-butylmercaptan and triethylamine. Treatment of I with sodium tellurophenolate in THF results in the formation of the ionic complex [(Cymen)Ru(μ-TePh)3Ru(Cymen)]+[(CO)3Re(μ-TePh)3Re(CO)3]− (III) with homobinuclear cation and anion. The structures of II and III were determined by X-ray diffraction (CIF files CCDC nos. 1022559 (II) and 1022560 (III)).

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Feb 13, 2015

References

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