ISSN 1070-4272, Russian Journal of Applied Chemistry, 2009, Vol. 82, No. 4, pp. 521−536. © Pleiades Publishing, Ltd., 2009. Original Russian Text © A.V. de Vekki, S.T. Marakaev, 2009, published in Zhurnal Prikladnoi Khimii, 2009, Vol. 82, No. 4, pp. 529−543. REVIEWS A. V. de Vekki and S. T. Marakaev All-Russia Research Institute of Petrochemical Processes, St. Petersburg, Russia Received April 11, 2008 DOI: 10.1134/S1070427209040016 CATALYTIC SYSTEMS FOR METHANE In contrast to the aforesaid, another mechanism of OXIDATION TO FORMALDEHYDE methane conversion can be found in the literature : CH → CH → CH O → CO + CO , in which the 4 4−x 2 2 activity of a catalyst is determined by the rate of the Formaldehyde is mostly manufactured from methanol, but, already in 1948, 20% of this compound was produced ﬁ rst reaction, and its selectivity by the ratio between by direct oxidation of gaseous hydrocarbons. However, the rates of the second and third stages of the process. the industrial process for manufacture of formaldehyde Detailed studies in this area have made it possible to verify the parallel-consecutive mechanism of the reaction by methane oxidation did not ﬁ nd use in the United of methane
Russian Journal of Applied Chemistry – Springer Journals
Published: May 19, 2009
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