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Catalytic oxidation of toluene by ozone in the acetic acid-sulfuric acid system

Catalytic oxidation of toluene by ozone in the acetic acid-sulfuric acid system Oxidation of toluene by ozone was studied in the system constituted by acetic and sulfuric acids in the presence of manganese(II) acetate and sodium bromide. The effect of sulfuric acid and the catalyst on the yield of benzoic acid and on the oxidation rate was considered. The optimal ozonization conditions were determined. A scheme of redox catalysis that accounts for experimental data was suggested. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Catalytic oxidation of toluene by ozone in the acetic acid-sulfuric acid system

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References (2)

Publisher
Springer Journals
Copyright
Copyright © 2011 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
DOI
10.1134/S1070427211060140
Publisher site
See Article on Publisher Site

Abstract

Oxidation of toluene by ozone was studied in the system constituted by acetic and sulfuric acids in the presence of manganese(II) acetate and sodium bromide. The effect of sulfuric acid and the catalyst on the yield of benzoic acid and on the oxidation rate was considered. The optimal ozonization conditions were determined. A scheme of redox catalysis that accounts for experimental data was suggested.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jul 16, 2011

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