Catalytic oxidation of p-xylene with molecular oxygen in the presence of N-hydroxyphthalimide

Catalytic oxidation of p-xylene with molecular oxygen in the presence of N-hydroxyphthalimide Relationships of p-xylene oxidation in the presence of N-hydroxyphthalimide and Co(II) and Mn(II) salts were studied. The activity of the catalytic system strongly depends on the volume of the ligand incorporated in the salt. The synergism in combined use of Co(II) and Mn(II) salts is observed only in the step of p-toluic acid oxidation, whereas replacement of a half of the Co(II) salt by the Mn(II) salt in p-xylene oxidation leads to additive increase in the reaction rate. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Catalytic oxidation of p-xylene with molecular oxygen in the presence of N-hydroxyphthalimide

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Publisher
Springer Journals
Copyright
Copyright © 2014 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427214070222
Publisher site
See Article on Publisher Site

Abstract

Relationships of p-xylene oxidation in the presence of N-hydroxyphthalimide and Co(II) and Mn(II) salts were studied. The activity of the catalytic system strongly depends on the volume of the ligand incorporated in the salt. The synergism in combined use of Co(II) and Mn(II) salts is observed only in the step of p-toluic acid oxidation, whereas replacement of a half of the Co(II) salt by the Mn(II) salt in p-xylene oxidation leads to additive increase in the reaction rate.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Oct 16, 2014

References

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