Catalytic degradation of polyethylene over ferrierite

Catalytic degradation of polyethylene over ferrierite The applicability of ferrierite to the catalytic degradation of polyethylenes, such as highdensity polyethylene (HDPE) and linear low-density polyethylene (LLDPE), and the effect of its acidity have been investigated using a thermogravimetric analyzer and batch reactor. Quantitative analyses of the products were also carried out using GC-MS and GC-FID. The apparent activation energy of the catalytic degradation of polyethylene was significantly lowered by the addition of the catalysts. Ferrierite, with a low SiO2/Al2O3 ratio, exhibited pronounced selectivity for the production of valuable olefins and excellent resistance to coke formation. All ferrierites generated mainly C6−C10 hydrocarbons, and seemed to have the catalytic stability in the degradation of polyethylene. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Catalytic degradation of polyethylene over ferrierite

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Publisher
Springer Netherlands
Copyright
Copyright © 2008 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/BF03036931
Publisher site
See Article on Publisher Site

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