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- Publisher
- Springer Journals
- Copyright
- Copyright © 2012 by Springer Science+Business Media B.V.
- Subject
- Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
- ISSN
- 0922-6168
- eISSN
- 1568-5675
- DOI
- 10.1007/s11164-012-0672-0
- Publisher site
- See Article on Publisher Site
Abstract
A series of transition metal-based catalysts, other than Pd or Pt-based catalysts, were investigated for catalytic amination of 2,6-dimethylphenol to 2,6-dimethylaniline in a fixed-bed reactor. Ni–Cu–Cr/γ-Al2O3 yielded satisfactory results with 82.08 % conversion and 47.24 % selectivity. The catalysts were characterized by H2-TPR and TEM, and the results obtained showed that the doped Cu and Cr could promote reduction of Ni/γ–Al2O3 and dispersion of the Ni. Reaction conditions, including reaction temperature, flow rate of hydrogen, and ammonia, were studied.
Journal
Research on Chemical Intermediates – Springer Journals
Published: Jul 4, 2012