Catalytic activity of systems based on titanium bis(phenoxy imine) complexes: Effect of the ligand structure

Catalytic activity of systems based on titanium bis(phenoxy imine) complexes: Effect of the... Polymerization of ethylene at 30–70°C in the presence of catalytic systems based on titanium bis(phenoxy imine) complexes of various structures, activated with methylalumoxane, was studied. An attempt was made to systematize the effect of substituents in ligands, to find correlations, to account for the results obtained, and to reveal conditions under which the reaction occurs by the living polymerization mechanism. Some properties and structural features of the polyethylenes obtained were determined. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Catalytic activity of systems based on titanium bis(phenoxy imine) complexes: Effect of the ligand structure

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2007 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427207090145
Publisher site
See Article on Publisher Site

Abstract

Polymerization of ethylene at 30–70°C in the presence of catalytic systems based on titanium bis(phenoxy imine) complexes of various structures, activated with methylalumoxane, was studied. An attempt was made to systematize the effect of substituents in ligands, to find correlations, to account for the results obtained, and to reveal conditions under which the reaction occurs by the living polymerization mechanism. Some properties and structural features of the polyethylenes obtained were determined.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Oct 17, 2007

References

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