Catal Lett (2017) 147:2332–2339 DOI 10.1007/s10562-017-2112-7 Catalytic Activity of Crystallographically Characterized Organic–Inorganic Hybrid Containing 1,5-Di-amino-pentane Tetrachloro Manganate with Perovskite Type Structure 1,4 2,3 4 1 Paramita Mondal · Seham Kamal Abdel-Aal · Debasis Das · Sk Manirul Islam Received: 27 March 2017 / Accepted: 9 June 2017 / Published online: 5 July 2017 © Springer Science+Business Media, LLC 2017 Abstract Layered 2D organic–inorganic hybrid perovs- catalytic activity towards sulphide and alkene oxidation kite (OIHS) of the diammonium series, 1,5 di-aminepen- using aqueous H O as an oxidant. 2 2 tane tetrachloro mangenate ([NH –(CH ) –NH] MnCl ) 3 2 5 3 4 Graphical Abstract OIHS of the diammonium series was prepared by slow evaporation and reducing tempera- [NH –(CH ) –NH] MnCl ; 1,5 di-aminepentane tetra- 3 2 5 3 4 ture method and characterized by single crystal X-ray dif- chloro mangenate were prepared by slow evaporation and fraction analysis. Its structure consists of organic cation, temperature decrease method, characterized by single crys- [NH (CH ) NH ] extended in a zigzag fashion and inor- 3 2 5 3 tal X-ray diffraction. This complex exhibits excellent cata- −2 2+ ganic anion, [MnCl ] where Mn is coordinated by six lytic activity towards sulphide oxidation and
Catalysis Letters – Springer Journals
Published: Jul 5, 2017
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