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H. Miura, Masashi Osawa, K. Sugiyama, T. Matsuda (1986)
The adsorption of CO and hydrogen on reduced molybdenum catalysts used for CO hydrogenationJournal of Catalysis, 101
M. Logan, A. Gellman, G. Somorjai (1985)
HYDROGENATION OF CARBON MONOXIDE ON Mo (100) SINGLE CRYSTALS AND POLYCRYSTALLINE FOILSJournal of Catalysis, 94
H. Storch (1951)
The Fischer-Tropsch and related syntheses
J. Dun, E. Gulari, K. Ng (1985)
Fischer-tropsch synthesis on charcoal-supported molybdenum: The effect of preparation conditions and potassium promotion on activity and selectivityApplied Catalysis, 15
C. Kellner, A. Bell (1982)
Effects of dispersion on the activity and selectivity of alumina-supported ruthenium catalysts for carbon monoxide hydrogenationJournal of Catalysis, 75
O. Okada, Ipponmatsu Masamichi, M. Kawai, K. Aika, T. Onishi (1984)
THE EFFECT OF STRONG INTERACTION BETWEEN Ru AND Al2O3 ON THE ACTIVITY FOR CARBON MONOXIDE HYDROGENATION OVER Ru/Al2O3Chemistry Letters, 13
G. Ranhotra, A. Bell, J. Reimer (1987)
Catalysis over molybdenum carbides and nitrides: II. Studies of CO hydrogenation and C2H6 hydrogenolysisJournal of Catalysis, 108
I. Kojima, E. Miyazaki (1984)
Catalysis by transition metal carbides: V. Kinetic measurements of hydrogenation of CO over TaC, TiC, and Mo2C catalystsJournal of Catalysis, 89
J. Lee, L. Volpe, F. Ribeiro, M. Boudart (1988)
Molybdenum carbide catalysts: II. Topotactic synthesis of unsupported powdersJournal of Catalysis, 112
J. Lee, K. Lee, J. Lee (1992)
SELECTIVE CHEMISORPTION OF CARBON-MONOXIDE AND HYDROGEN OVER SUPPORTED MOLYBDENUM CARBIDE CATALYSTSThe Journal of Physical Chemistry, 96
M. Saito, R. Anderson (1981)
The activity of several molybdenum compounds for the methanation of CO2Journal of Catalysis, 67
M. Vannice (1976)
The catalytic synthesis of hydrocarbons from H2CO mixtures over the group VIII metals: IV. The kinetic behavior of CO hydrogenation over Ni catalystsJournal of Catalysis, 44
J. Lee, S. Locatelli, S. Oyama, M. Boudart (1990)
Molybdenum carbide catalysts 3. Turnover rates for the hydrogenolysis of n-butaneJournal of Catalysis, 125
R. Bowman, R. Burwell (1980)
The reaction between hydrogen and carbon monoxide on catalysts derived from Mo(CO)6Al2O3Journal of Catalysis, 63
M. Boudart, J. Lee, K. Imura, S. Yoshida (1987)
The effect of surface composition on the chemisorption of hydrogen on tungsten carbideJournal of Catalysis, 103
M. Vannice (1975)
The catalytic synthesis of hydrocarbons from H2CO mixtures over the group VIII metals: I. The specific activities and product distributions of supported metalsJournal of Catalysis, 37
R. Betta, A. Piken, M. Shelef (1974)
Heterogeneous methanation: initial rate of CO hydrogenation on supported ruthenium and nickelJournal of Catalysis, 35
T. Thomas, A. Brenner (1983)
Well-dispersed catalysts of supported chromium, molybdenum and tungsten carbonyls which are highly active for alkene hydrogenationJournal of Molecular Catalysis, 18
J. Lee, M. Yeom, D.S. Lee (1990)
Catalysis by Molybdenum Carbide in Activation of C-C, C-O and C-H bondsJournal of Molecular Catalysis, 62
B. Concha, G. Bartholomew, C. Bartholomew (1984)
CO hydrogenation on supported molybdenum catalysts: Effects of support on specific activities of reduced and sulfided catalystsJournal of Catalysis, 89
A. Bridgewater, R. Burch, P. Mitchell (1982)
Reactions of carbon monoxide with hydrogen over molybdenum/charcoal catalystsJournal of Catalysis, 78
J. Lee, M. Boudart (1993)
In situ carburization of metallic molybdenum during catalytic reactions of carbon-containing gasesCatalysis Letters, 20
P. Biloen, W. Sachtler (1982)
Mechanism of Hydrocarbon Synthesis over Fischer-Tropsch CatalystsAdvances in Catalysis, 30
L. Leclereq, K. Imura, S. Yoshida, T. Barbee, M. Boudart (1979)
Preparation of Catalysis II
M. Boudart, M. Mcdonald (1984)
Structure sensitivity of hydrocarbon synthesis from carbon monoxide and hydrogenThe Journal of Physical Chemistry, 88
R. Anderson, H. Kölbel, M. Rálek (1984)
The Fischer-Tropsch Synthesis
E. Ko, R. Madix (1981)
Effects of adsorbed carbon and oxygen on the chemisorption of H2 and Co on Mo(100)Surface Science, 109
Supported and unsupported molybdenum and molybdenum carbides have been studied as catalysts of CO-H2 reactions at 570 K and atmospheric pressure. The initial turnover rates of these catalysts were comparable to those of the more active group VIII elements. However, all molybdenum-based catalysts showed a hydrocarbon product distribution different from those for typical group VIII metals. Furthermore, production of a large amount of CO2 (instead of water) and a high paraffin/olefin ratio reflected high activities of these catalysts for the water-gas shift reaction and hydrogenation, respectively. The high water-gas shift reaction activity allowed a CO-rich synthesis gas to be used efficiently over Mo-based catalysts. The CO-H2 reactions appear to be structure insensitive on molybdenum carbide catalysts, since the rates were independent of particle size and crystal structure of unsupported catalysts and of metal loading of supported catalysts.
Research on Chemical Intermediates – Springer Journals
Published: Jan 1, 2000
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