The method of isothermal calorimetry at dilutions (moles salt/moles water) of 1:9000, 1:18000, and 1:36000 was applied to study the heats of solution of methyl iodides of dimethyl-and diethylamino grosshemin. The data obtained were used to calculate the standard enthalpies of solution of C18H28O4NI and C20H32O4NI in an infinitely diluted (standard) aqueous solution. The heats of combustion and melting of C18H28O4NI and C20H32O4NI were estimated. The experimental and calculational techniques were combined to calculate the standard heats of formation of methyl iodides of dimethyl-and diethylamino grosshemin and their 66 analogues.
Russian Journal of Applied Chemistry – Springer Journals
Published: Sep 28, 2006
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