Calorimetric study of the enthalpies of solution of methyl iodides of dimethylamino grosshemin and diethylamino grosshemin in water and evaluation of the thermodynamic properties of their analogues

Calorimetric study of the enthalpies of solution of methyl iodides of dimethylamino grosshemin... The method of isothermal calorimetry at dilutions (moles salt/moles water) of 1:9000, 1:18000, and 1:36000 was applied to study the heats of solution of methyl iodides of dimethyl-and diethylamino grosshemin. The data obtained were used to calculate the standard enthalpies of solution of C18H28O4NI and C20H32O4NI in an infinitely diluted (standard) aqueous solution. The heats of combustion and melting of C18H28O4NI and C20H32O4NI were estimated. The experimental and calculational techniques were combined to calculate the standard heats of formation of methyl iodides of dimethyl-and diethylamino grosshemin and their 66 analogues. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Calorimetric study of the enthalpies of solution of methyl iodides of dimethylamino grosshemin and diethylamino grosshemin in water and evaluation of the thermodynamic properties of their analogues

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427206080052
Publisher site
See Article on Publisher Site

Abstract

The method of isothermal calorimetry at dilutions (moles salt/moles water) of 1:9000, 1:18000, and 1:36000 was applied to study the heats of solution of methyl iodides of dimethyl-and diethylamino grosshemin. The data obtained were used to calculate the standard enthalpies of solution of C18H28O4NI and C20H32O4NI in an infinitely diluted (standard) aqueous solution. The heats of combustion and melting of C18H28O4NI and C20H32O4NI were estimated. The experimental and calculational techniques were combined to calculate the standard heats of formation of methyl iodides of dimethyl-and diethylamino grosshemin and their 66 analogues.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Sep 28, 2006

References

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