Building MOF bottles (MIL-101 family as heterogeneous single-site catalysts) around Fe3O4 ships: A highly efficient and magnetically separable catalyst for oxidation of alcohols

Building MOF bottles (MIL-101 family as heterogeneous single-site catalysts) around Fe3O4 ships:... Fe3O4 supported on chromium-based metal-organic framework (MOF), MIL-101(Cr), has emerged as highly efficient and heterogeneous catalyst for selective oxidation of alcohols because of its high specific surface area, tuneable pore size, and unique structure. MIL-101 and its Fe3O4 composite (Fe3O4@MIL-101) was prepared via the impregnation of the Fe3O4 in MIL-101. The surface properties of the functionalized catalyst were analyzed by a series of characterization techniques like FTIR, XRD, N2 adsorption–desorption, and TEM. XRD and adsorption–desorption analysis show that the mesostructure of MIL-101 remains intact after Fe3O4 modifications, while spectral technique show the successful immobilizing of the neat Fe3O4 inside the MIL-101 support. Fe3O4@MIL-101 can be reused several times although they get less active. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Building MOF bottles (MIL-101 family as heterogeneous single-site catalysts) around Fe3O4 ships: A highly efficient and magnetically separable catalyst for oxidation of alcohols

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427215080194
Publisher site
See Article on Publisher Site

Abstract

Fe3O4 supported on chromium-based metal-organic framework (MOF), MIL-101(Cr), has emerged as highly efficient and heterogeneous catalyst for selective oxidation of alcohols because of its high specific surface area, tuneable pore size, and unique structure. MIL-101 and its Fe3O4 composite (Fe3O4@MIL-101) was prepared via the impregnation of the Fe3O4 in MIL-101. The surface properties of the functionalized catalyst were analyzed by a series of characterization techniques like FTIR, XRD, N2 adsorption–desorption, and TEM. XRD and adsorption–desorption analysis show that the mesostructure of MIL-101 remains intact after Fe3O4 modifications, while spectral technique show the successful immobilizing of the neat Fe3O4 inside the MIL-101 support. Fe3O4@MIL-101 can be reused several times although they get less active.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Nov 21, 2015

References

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