Boron trifluoride supported on hydroxyapatite-encapsulated-γ-Fe2O3 as a magnetically recoverable catalyst for ring opening of α,β-epoxy ketones

Boron trifluoride supported on hydroxyapatite-encapsulated-γ-Fe2O3 as a magnetically recoverable... Catalytic ring opening reactions of α-epoxyketones by boron trifluoride supported on hydroxyapatite-encapsulated-γ-Fe2O3 [γ-Fe2O3@HAp-BF3 −CH3OH2 +] as a heterogeneous, reusable and highly efficient catalyst in methanol solution at room temperature resulted in the formation of α-hydroxyl-β-methoxyketones through Cβ-O cleavage in excellent yields. The catalyst can be easily separated by a magnet and reused for several cycles. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Boron trifluoride supported on hydroxyapatite-encapsulated-γ-Fe2O3 as a magnetically recoverable catalyst for ring opening of α,β-epoxy ketones

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Publisher
Springer Netherlands
Copyright
Copyright © 2014 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-014-1577-x
Publisher site
See Article on Publisher Site

Abstract

Catalytic ring opening reactions of α-epoxyketones by boron trifluoride supported on hydroxyapatite-encapsulated-γ-Fe2O3 [γ-Fe2O3@HAp-BF3 −CH3OH2 +] as a heterogeneous, reusable and highly efficient catalyst in methanol solution at room temperature resulted in the formation of α-hydroxyl-β-methoxyketones through Cβ-O cleavage in excellent yields. The catalyst can be easily separated by a magnet and reused for several cycles.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Mar 19, 2014

References

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