New oxyquinoline boron complexes Mes2BQ (I) and Mes2BQMe (II), where QH is 8-hydroxyquinoline and QMeH is 2-methyl-8-hydroxyquinoline, (CIF files CCDC 1051351 (I) and 1051352 (II)) are synthesized and structurally characterized. Their photoluminescence (PL) and electroluminescence (EL) properties are studied. The compounds have an intense green PL. The EL characteristics of complexes I and II doped in poly-N-vinylcarbazole (PVK) differ substantially. Compound I generates green luminescence with a brightness of 356 cd/m2, whereas white EL with a brightness of 36 cd/m2 is observed in the case of compound II.
Russian Journal of Coordination Chemistry – Springer Journals
Published: Oct 11, 2015
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