Boron complexes with mesityl and oxyquinoline ligands: Syntheses, structures, and luminescence properties

Boron complexes with mesityl and oxyquinoline ligands: Syntheses, structures, and luminescence... New oxyquinoline boron complexes Mes2BQ (I) and Mes2BQMe (II), where QH is 8-hydroxyquinoline and QMeH is 2-methyl-8-hydroxyquinoline, (CIF files CCDC 1051351 (I) and 1051352 (II)) are synthesized and structurally characterized. Their photoluminescence (PL) and electroluminescence (EL) properties are studied. The compounds have an intense green PL. The EL characteristics of complexes I and II doped in poly-N-vinylcarbazole (PVK) differ substantially. Compound I generates green luminescence with a brightness of 356 cd/m2, whereas white EL with a brightness of 36 cd/m2 is observed in the case of compound II. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Boron complexes with mesityl and oxyquinoline ligands: Syntheses, structures, and luminescence properties

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415100061
Publisher site
See Article on Publisher Site

Abstract

New oxyquinoline boron complexes Mes2BQ (I) and Mes2BQMe (II), where QH is 8-hydroxyquinoline and QMeH is 2-methyl-8-hydroxyquinoline, (CIF files CCDC 1051351 (I) and 1051352 (II)) are synthesized and structurally characterized. Their photoluminescence (PL) and electroluminescence (EL) properties are studied. The compounds have an intense green PL. The EL characteristics of complexes I and II doped in poly-N-vinylcarbazole (PVK) differ substantially. Compound I generates green luminescence with a brightness of 356 cd/m2, whereas white EL with a brightness of 36 cd/m2 is observed in the case of compound II.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Oct 11, 2015

References

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