Bis[di(hydroxymethyl)phosphinato]diaquacobalt(II), [Co(H2O)2{(HOCH2)2PO2}2]: Synthesis, properties, and crystal structure

Bis[di(hydroxymethyl)phosphinato]diaquacobalt(II), [Co(H2O)2{(HOCH2)2PO2}2]: Synthesis,... The synthesis and some properties of the Co(II) complex with di(hydroxymethyl)phosphinic acid (HL) of the composition CoL2·2H2O are described. X-ray powder diffraction analysis confirmed the phase homogeneity of the polycrystalline sample. The crystal structure is determined by X-ray diffraction method. The Co atom is located in the center of octahedron formed by the O atoms of two ligands L and of two water molecules. The ligand L performs bidentate-chelate function and is bonded to the Co atom through the O atoms of the phosphinate group and of one alcohol group. Russian Journal of Coordination Chemistry Springer Journals

Bis[di(hydroxymethyl)phosphinato]diaquacobalt(II), [Co(H2O)2{(HOCH2)2PO2}2]: Synthesis, properties, and crystal structure

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Copyright © 2006 by Pleiades Publishing, Inc.
Chemistry; Inorganic Chemistry; Physical Chemistry
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