Autothermal reforming of methane to syngas for Fischer-Tropsch synthesis with promoted palladium and a fast start-up device

Autothermal reforming of methane to syngas for Fischer-Tropsch synthesis with promoted palladium... In this study, a Pd catalyst was prepared with promoters such as CeO2, BaO and SrO in a washcoated form on a metallic monolith for autothermal reforming of methane to syngas for the Fischer-Tropsch synthesis. A reactor was installed with an electric heater in the form of the metallic monolith as a start-up device instead of a burner with which stable and fast start-ups (within 4 min) were achieved. Gas hourly space velocity and O2/CH4 governed, methane conversion, while H2O/CH4 controlled H2/CO ratio. A methane conversion of approx. 96%, H2+CO selectivity of approx. 85%, and H2/CO of approx. 2.6 were obtained under the conditions of gas hourly space velocity (GHSV) at 103000 h−1, O2/CH4=0.7 and H2O/CH4=0.35. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Autothermal reforming of methane to syngas for Fischer-Tropsch synthesis with promoted palladium and a fast start-up device

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Publisher
Springer Netherlands
Copyright
Copyright © 2008 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/BF03036941
Publisher site
See Article on Publisher Site

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