Asymmetric Henry reaction catalyzed by oxazolinyl Cu(II) complexes

Asymmetric Henry reaction catalyzed by oxazolinyl Cu(II) complexes A novel family of oxazolinyl copper(II) catalysts have been developed and used as Lewis acid catalysts in the asymmetric Henry reaction of various aldehydes with nitromethane. The corresponding nitroalcohol products were obtained in moderate yields (40–80%) and with moderate enantioselectivity (10–40% ee). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Asymmetric Henry reaction catalyzed by oxazolinyl Cu(II) complexes

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Publisher
Springer Netherlands
Copyright
Copyright © 2009 by Springer Science+Business Media B.V.
Subject
Chemistry; Inorganic Chemistry ; Physical Chemistry ; Catalysis
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-008-0008-2
Publisher site
See Article on Publisher Site

Abstract

A novel family of oxazolinyl copper(II) catalysts have been developed and used as Lewis acid catalysts in the asymmetric Henry reaction of various aldehydes with nitromethane. The corresponding nitroalcohol products were obtained in moderate yields (40–80%) and with moderate enantioselectivity (10–40% ee).

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Jan 21, 2009

References

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