Assistant effect on modulating the two Mn(II) complexes

Assistant effect on modulating the two Mn(II) complexes Two Mn-based complexes with chemical formulae {[Mn(L1)2(H2O)(4,4'-Bipy)] · 3H2O} (I) and [Mn(L2)2(H2O)2(4,4'-Bipy)] (II) (HL1 = 3-(4-hydroxyphenyl)propanoic acid, HL2 = p-hydroxy phenylacetic acid, 4,4'-Bipy = 4,4'-bipyridine), have been synthesized and are characterized by single crystal X-ray diffraction (CIF files CCDC nos. 1045594 (I), 1045595 (II)). Compounds I has 1D zigzag chain constructed by bridging bisdentated 4,4'-Bipy linkers, whereas II shows mononuclear motif due to the monodentated 4,4'-Bipy mode. The assistant effect of the flexibility of carboxylate may play an important to modulate on the resulting motif. Russian Journal of Coordination Chemistry Springer Journals

Assistant effect on modulating the two Mn(II) complexes

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Pleiades Publishing
Copyright © 2015 by Pleiades Publishing, Ltd.
Chemistry; Physical Chemistry; Inorganic Chemistry
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