Application of capillary electrophoresis to the separation of rhenium complex of 1,2,3-trihydroxybenzene

Application of capillary electrophoresis to the separation of rhenium complex of... Monatsh Chem (2017) 148:1619–1624 DOI 10.1007/s00706-017-1982-0 OR IGINAL PAPER Application of capillary electrophoresis to the separation of rhenium complex of 1,2,3-trihydroxybenzene 1 2 1 2 1 • • • • David Kaliba Martin Stı´cha Ivan Jelı´nek Jana Pola´kova´ Jana Radova´ Received: 26 January 2017 / Accepted: 10 April 2017 / Published online: 4 July 2017 Springer-Verlag Wien 2017 Abstract A capillary zone electrophoretic method has Keywords Capillary zone electrophoresis been developed for a separation of a reaction mixture of a Coordination chemistry  Metal complexes rhenium complex. The rhenium complex was synthesized Organometallic compounds  Transitions metal compounds in a reaction of a rhenium precursor and 1,2,3-trihydrox- ybenzene in acetonitrile with triethylamine addition. The capillary electrophoretic method has been used for the Introduction separation in borate and phosphate buffer (pH 6.30–11.80). All components in the reaction mixture (unreacted pre- Medical inorganic chemistry is rapidly developing. It offers cursor, ligand, and final rhenium complex) have been new possibilities in pharmaceutical industries, which have determined by capillary zone electrophoresis with UV–Vis been traditionally dominated by organic chemistry so far. detection in an aqueous running electrolyte within 10 min. In developing diagnostics radiopharmaceuticals, a rising Dependencies of effective electrophoretic ion mobility on http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Monatshefte für Chemie - Chemical Monthly Springer Journals

Application of capillary electrophoresis to the separation of rhenium complex of 1,2,3-trihydroxybenzene

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Publisher
Springer Vienna
Copyright
Copyright © 2017 by Springer-Verlag Wien
Subject
Chemistry; Chemistry/Food Science, general; Organic Chemistry; Inorganic Chemistry; Analytical Chemistry; Physical Chemistry; Theoretical and Computational Chemistry
ISSN
0026-9247
eISSN
1434-4475
D.O.I.
10.1007/s00706-017-1982-0
Publisher site
See Article on Publisher Site

Abstract

Monatsh Chem (2017) 148:1619–1624 DOI 10.1007/s00706-017-1982-0 OR IGINAL PAPER Application of capillary electrophoresis to the separation of rhenium complex of 1,2,3-trihydroxybenzene 1 2 1 2 1 • • • • David Kaliba Martin Stı´cha Ivan Jelı´nek Jana Pola´kova´ Jana Radova´ Received: 26 January 2017 / Accepted: 10 April 2017 / Published online: 4 July 2017 Springer-Verlag Wien 2017 Abstract A capillary zone electrophoretic method has Keywords Capillary zone electrophoresis been developed for a separation of a reaction mixture of a Coordination chemistry  Metal complexes rhenium complex. The rhenium complex was synthesized Organometallic compounds  Transitions metal compounds in a reaction of a rhenium precursor and 1,2,3-trihydrox- ybenzene in acetonitrile with triethylamine addition. The capillary electrophoretic method has been used for the Introduction separation in borate and phosphate buffer (pH 6.30–11.80). All components in the reaction mixture (unreacted pre- Medical inorganic chemistry is rapidly developing. It offers cursor, ligand, and final rhenium complex) have been new possibilities in pharmaceutical industries, which have determined by capillary zone electrophoresis with UV–Vis been traditionally dominated by organic chemistry so far. detection in an aqueous running electrolyte within 10 min. In developing diagnostics radiopharmaceuticals, a rising Dependencies of effective electrophoretic ion mobility on

Journal

Monatshefte für Chemie - Chemical MonthlySpringer Journals

Published: Jul 4, 2017

References

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