New experimental data characterizing the conditions of electrochemical synthesis of stable electrically conducting electrochromic polymeric film systems based on the complexes [Ni(Salpn-1,3)] and [Cu(Salpn-1,3)] [Salpn-1,3 is N,N′-propylenebis(salicylidenimine)] in a 0.1 M Bu4NClO4/CH2Cl2 solution are presented. The redox conductivity of the new polymers is characterized by the charge diffusion coefficient. The electrochemical stability of the polymeric films is analyzed in relation to the potential and time of accumulation, and also to the range of potential sweeping.
Russian Journal of Applied Chemistry – Springer Journals
Published: Mar 22, 2005
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