Analyzing the anodic reactions for iron surface with a porous Al2O3 cluster with the scanning vibrating electrode

Analyzing the anodic reactions for iron surface with a porous Al2O3 cluster with the scanning... Appl. Phys. A (2017) 123:585 DOI 10.1007/s00339-017-1202-0 Analyzing the anodic reactions for iron surface with a porous Al O cluster with the scanning vibrating electrode 2 3 Faysal Fayez Eliyan Received: 4 June 2017 / Accepted: 14 August 2017 Springer-Verlag GmbH Germany 2017 Abstract The Scanning Vibrating Electrode Technique Graphical abstract (SVET) was used to analyze the anodic reactions inside and around a porous Al O cluster embedded onto an iron 2 3 foil. The tests were carried out at -0.7 V vs. Saturated Calomel Electrode, in naturally aerated solutions of 0.1, 0.2, 0.35, and 0.5 M bicarbonate concentration. During 10 h of testing, the SVET showed evidence for a formation of a passive film in and around the cluster, in the scanning area shown in the graphical abstract. In the dilute 0.1 and 0.2 M solutions, the passive films formed slower than those in 0.35 and 0.5 M solutions. In the SVET maps, the passive films showed that they could suppress dissolution to cur- rents comparable to those of slower dissolution under the porous Al O cluster. 2 3 1 Introduction The Scanning Vibrating Electrode Technique (SVET) is an electrochemical method used to measure the electro-reac- tivity of http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Applied Physics A: Materials Science Processing Springer Journals

Analyzing the anodic reactions for iron surface with a porous Al2O3 cluster with the scanning vibrating electrode

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Publisher
Springer Berlin Heidelberg
Copyright
Copyright © 2017 by Springer-Verlag GmbH Germany
Subject
Physics; Condensed Matter Physics; Optical and Electronic Materials; Nanotechnology; Characterization and Evaluation of Materials; Surfaces and Interfaces, Thin Films; Operating Procedures, Materials Treatment
ISSN
0947-8396
eISSN
1432-0630
D.O.I.
10.1007/s00339-017-1202-0
Publisher site
See Article on Publisher Site

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