All-solid-state battery Li–Ga–Ag | Li7La3Zr2O12 + Li2O–Y2O3–SiO2 | Li2O–V2O5–B2O3

All-solid-state battery Li–Ga–Ag | Li7La3Zr2O12 + Li2O–Y2O3–SiO2 | Li2O–V2O5–B2O3 Electrochemical cell Li–Ga–Ag | Li7La3Zr2O12 + 5 wt % 40.2Li2O·5.7Y2O3·54.1SiO2 glass | 25Li2O·30B2O3·45V2O5 glass ceramic was studied. The glassy materials 40.2Li2O·5.7Y2O3·54.1SiO2 and 25Li2O·30B2O3·45V2O5 were produced by melt quenching. The use of a glassy cathode based on vanadium oxide enabled a close contact between the cathode and the solid electrolyte. At a temperature of 280°C, the electrochemical cell under study can be charged to 3.33 V. It was found that the deintercalation of lithium is hindered in the course of charging and discharge. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

All-solid-state battery Li–Ga–Ag | Li7La3Zr2O12 + Li2O–Y2O3–SiO2 | Li2O–V2O5–B2O3

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/lp/springer_journal/all-solid-state-battery-li-ga-ag-li7la3zr2o12-li2o-y2o3-sio2-li2o-v2o5-pv86hKS7MJ
Publisher
Pleiades Publishing
Copyright
Copyright © 2016 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427216090081
Publisher site
See Article on Publisher Site

Abstract

Electrochemical cell Li–Ga–Ag | Li7La3Zr2O12 + 5 wt % 40.2Li2O·5.7Y2O3·54.1SiO2 glass | 25Li2O·30B2O3·45V2O5 glass ceramic was studied. The glassy materials 40.2Li2O·5.7Y2O3·54.1SiO2 and 25Li2O·30B2O3·45V2O5 were produced by melt quenching. The use of a glassy cathode based on vanadium oxide enabled a close contact between the cathode and the solid electrolyte. At a temperature of 280°C, the electrochemical cell under study can be charged to 3.33 V. It was found that the deintercalation of lithium is hindered in the course of charging and discharge.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jan 3, 2017

References

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