A simple and efficient catalytic system including 3-methyl-4-oxa-5-azahomoadamantane and FeCl3 for aerobic oxidative synthesis of benzimidazoles from primary amines and o-phenylenediamine is presented. This process uses O2 as economic and green oxidant and water as green solvent, tolerates a wide range of substrates, and can afford the target products in moderate to excellent yields.
Research on Chemical Intermediates – Springer Journals
Published: Apr 11, 2015
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