Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

Adsorption of lead(II), cadmium(II) and dysprosium(III) from aqueous solutions using mesoporous silica modified with phosphonic acid groups

Adsorption of lead(II), cadmium(II) and dysprosium(III) from aqueous solutions using mesoporous... The mesoporous silica samples with different concentrations of phosphonic acid groups on the surface were obtained by direct template synthesis. The block-copolymer Pluronic P123 was used as a template, and sodium meta-silicate with diethylphosphatoethyltriethoxysilane as precursors. According to the SAXS diffractograms, mesoporous silica samples have a p6mm hexagonal symmetry. In addition, we used sol–gel method to synthesize xerogel with the same groups for comparison. All samples possess high values of specific surface area 615–730 m2/g and sorption pore volume. FTIR and potentiometric titration methods were used to investigate the surface layer of these samples. Sorption properties of the samples with phosphonic acid groups were studied in respect to a row of metal cations, among which we focused on lead(II), cadmium(II), and dysprosium(III) cations. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Sol-Gel Science and Technology Springer Journals

Adsorption of lead(II), cadmium(II) and dysprosium(III) from aqueous solutions using mesoporous silica modified with phosphonic acid groups

Loading next page...
 
/lp/springer_journal/adsorption-of-lead-ii-cadmium-ii-and-dysprosium-iii-from-aqueous-oBCucs2bCk

References (50)

Publisher
Springer Journals
Copyright
Copyright © 2018 by Springer Science+Business Media, LLC, part of Springer Nature
Subject
Materials Science; Ceramics, Glass, Composites, Natural Materials; Inorganic Chemistry; Optical and Electronic Materials; Nanotechnology
ISSN
0928-0707
eISSN
1573-4846
DOI
10.1007/s10971-018-4692-0
Publisher site
See Article on Publisher Site

Abstract

The mesoporous silica samples with different concentrations of phosphonic acid groups on the surface were obtained by direct template synthesis. The block-copolymer Pluronic P123 was used as a template, and sodium meta-silicate with diethylphosphatoethyltriethoxysilane as precursors. According to the SAXS diffractograms, mesoporous silica samples have a p6mm hexagonal symmetry. In addition, we used sol–gel method to synthesize xerogel with the same groups for comparison. All samples possess high values of specific surface area 615–730 m2/g and sorption pore volume. FTIR and potentiometric titration methods were used to investigate the surface layer of these samples. Sorption properties of the samples with phosphonic acid groups were studied in respect to a row of metal cations, among which we focused on lead(II), cadmium(II), and dysprosium(III) cations.

Journal

Journal of Sol-Gel Science and TechnologySpringer Journals

Published: Jun 1, 2018

There are no references for this article.