Adsorption of haloadamantanes on the basal face of graphite

Adsorption of haloadamantanes on the basal face of graphite The graphite surface exhibits different structural selectivity to isomeric haloadamantanes depending on the kind and number of halogen atoms in the molecule. In the series of fluoro-, chloro-, bromo-, and iodoadamantanes, the selectivity of separation of the respective isomers on columns packed with graphitized thermal soot increases. The equilibrium adsorption characteristics of haloadamantanes (adsorption equilibrium constants, heats and entropies of adsorption), calculated within the framework of molecular-statistical theory, agree well with the experimental values and allow comprehensive description of the adsorbed state of these compounds on the graphite surface. The results of molecular-statistical calculations allow evaluating the possibility of haloadamantane separation on columns with graphitized thermal soot under the conditions of equilibrium gas-adsorption chromatography. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Adsorption of haloadamantanes on the basal face of graphite

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2013 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427213030245
Publisher site
See Article on Publisher Site

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