Active control of catalysis and product selectivity by a fuel cell system

Active control of catalysis and product selectivity by a fuel cell system A new concept to control catalysis and catalytic reaction through partial oxidation of alkenes with O2 is described. Oxidation of alkenes was studied by alkene/Pd-anode/H3PO4-electrolyte/cathode/O2 fuel cell (FC). An idea based on electrocatalysis and electrochemical reactions to control reaction rates and product selectivity was proposed and proven through the oxidation of propylene, Wacker and π-allyl oxidation. The oxidation rate and the product selectivity to the Wacker and the π-allyl oxidations could be controlled by changing electrode potentials. We could active control oxidation states of Pd on the anode, Pd(II) or Pd(0), during the oxidation from outer circuit. The oxidation states of Pd on the anode decided the product selectivity. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Active control of catalysis and product selectivity by a fuel cell system

Loading next page...
 
/lp/springer_journal/active-control-of-catalysis-and-product-selectivity-by-a-fuel-cell-NfCnXbaKvo
Publisher
Springer Netherlands
Copyright
Copyright © 2006 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856706777346534
Publisher site
See Article on Publisher Site

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

Monthly Plan

  • Read unlimited articles
  • Personalized recommendations
  • No expiration
  • Print 20 pages per month
  • 20% off on PDF purchases
  • Organize your research
  • Get updates on your journals and topic searches

$49/month

Start Free Trial

14-day Free Trial

Best Deal — 39% off

Annual Plan

  • All the features of the Professional Plan, but for 39% off!
  • Billed annually
  • No expiration
  • For the normal price of 10 articles elsewhere, you get one full year of unlimited access to articles.

$588

$360/year

billed annually
Start Free Trial

14-day Free Trial