Acid strength of Ni–S2O 8 2− /ZrO2 catalyst and its catalytic activity for n-pentane isomerization

Acid strength of Ni–S2O 8 2− /ZrO2 catalyst and its catalytic activity for n-pentane... A series of bifunctional Ni–S2O8 2−/ZrO2 (Ni x -SSZ-T) catalysts with different Ni mass fraction (x, %) and calcintion temperature (T, °C) were prepared by impregnation method. The catalysts were characterized by XRD, FTIR, and py-FTIR. The effects of Ni content and calcination temperature on the acidic property and isomerization performance of catalyst were investigated using n-pentane isomerization as a probe reaction. The results show that the acidity of Ni x -SSZ-T catalysts mainly derives from L acid. The addition of a suitable amount of Ni can induce the formation of more acid sites and in turn enhance the isomerization performance of Ni x -SSZ-T catalyst. With increasing the calcination temperature from 550 to 700°C, B acid strength of catalyst weakens gradually, while the L acid strength increases first and then decreases. The Ni x -SSZ-T catalyst with Ni content of 1 wt % and calcination temperature of 650°C exhibits the best isomerization performance. At reaction temperature of 230°C, pressure of 2. 0 MPa hydrogen /hydrocarbon molar ratio of 4: 1, and weight hourly space velocity (WHSV) of 1.0 h−1 the isopentane yield reaches 57.0%. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Acid strength of Ni–S2O 8 2− /ZrO2 catalyst and its catalytic activity for n-pentane isomerization

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Publisher
Pleiades Publishing
Copyright
Copyright © 2016 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427216040224
Publisher site
See Article on Publisher Site

Abstract

A series of bifunctional Ni–S2O8 2−/ZrO2 (Ni x -SSZ-T) catalysts with different Ni mass fraction (x, %) and calcintion temperature (T, °C) were prepared by impregnation method. The catalysts were characterized by XRD, FTIR, and py-FTIR. The effects of Ni content and calcination temperature on the acidic property and isomerization performance of catalyst were investigated using n-pentane isomerization as a probe reaction. The results show that the acidity of Ni x -SSZ-T catalysts mainly derives from L acid. The addition of a suitable amount of Ni can induce the formation of more acid sites and in turn enhance the isomerization performance of Ni x -SSZ-T catalyst. With increasing the calcination temperature from 550 to 700°C, B acid strength of catalyst weakens gradually, while the L acid strength increases first and then decreases. The Ni x -SSZ-T catalyst with Ni content of 1 wt % and calcination temperature of 650°C exhibits the best isomerization performance. At reaction temperature of 230°C, pressure of 2. 0 MPa hydrogen /hydrocarbon molar ratio of 4: 1, and weight hourly space velocity (WHSV) of 1.0 h−1 the isopentane yield reaches 57.0%.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jul 15, 2016

References

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