A three-dimensional coordination polymer based on 3,5-pyrazoledicarboxylic acid (H3Pdc): [Cd2(HPdc)1.5Cl(H2O)2] n

A three-dimensional coordination polymer based on 3,5-pyrazoledicarboxylic acid (H3Pdc):... The title coordination polymer, [Cd2(HPdc)1.5Cl(H2O)2] n (I) (H3Pdc = 3,5-pyrazoledicarboxylic acid), has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction (CIF file CCDC no. 1037505). Complex I crystallizes in orthorhombic space group Pbcn with a = 10.2631(11), b = 17.1997(18), c = 14.3044(15) Å, V = 2525.0(5) Å3, C15H14Cd4Cl2N6O16, M = 1054.82, ρc = 2.775 g/cm3, μ(MoK α) = 3.627 mm−1, F(000) = 2000, GOOF = 1.067, Z = 4, the final R 1 = 0.0562 and wR 2 = 0.1301 for I > 2σ(I). The Cd(1) ions and HPdc2- ligands connect to form a serial of the 2D corrugated 63 sheets packing parallel along the z axis. Each 63 sheet is connected with the two neighboring sheets by the Cl− and Cd(2) ions to construct the 3D framework of I. The 3D structure can also be rationalized as a 4-connected trinodal ( topological network (the long Schläfli symbol is ( by considering the Cd(1), Cd(2) ions and HPdc2− ligands as 4-connected nodes, the Cl− ions as linkers, respectively. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

A three-dimensional coordination polymer based on 3,5-pyrazoledicarboxylic acid (H3Pdc): [Cd2(HPdc)1.5Cl(H2O)2] n

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Pleiades Publishing
Copyright © 2015 by Pleiades Publishing, Ltd.
Chemistry; Physical Chemistry; Inorganic Chemistry
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