A three-dimensional coordination polymer based on 3,5-pyrazoledicarboxylic acid (H3Pdc): [Cd2(HPdc)1.5Cl(H2O)2] n

A three-dimensional coordination polymer based on 3,5-pyrazoledicarboxylic acid (H3Pdc):... The title coordination polymer, [Cd2(HPdc)1.5Cl(H2O)2] n (I) (H3Pdc = 3,5-pyrazoledicarboxylic acid), has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction (CIF file CCDC no. 1037505). Complex I crystallizes in orthorhombic space group Pbcn with a = 10.2631(11), b = 17.1997(18), c = 14.3044(15) Å, V = 2525.0(5) Å3, C15H14Cd4Cl2N6O16, M = 1054.82, ρc = 2.775 g/cm3, μ(MoK α) = 3.627 mm−1, F(000) = 2000, GOOF = 1.067, Z = 4, the final R 1 = 0.0562 and wR 2 = 0.1301 for I > 2σ(I). The Cd(1) ions and HPdc2- ligands connect to form a serial of the 2D corrugated 63 sheets packing parallel along the z axis. Each 63 sheet is connected with the two neighboring sheets by the Cl− and Cd(2) ions to construct the 3D framework of I. The 3D structure can also be rationalized as a 4-connected trinodal (4.5.72.8.9)(4.52.62.7)(4.5.6.73) topological network (the long Schläfli symbol is (4.5.7.7.102)(4.124.5.6.5.7)(4.5.6.7.7.7)) by considering the Cd(1), Cd(2) ions and HPdc2− ligands as 4-connected nodes, the Cl− ions as linkers, respectively. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

A three-dimensional coordination polymer based on 3,5-pyrazoledicarboxylic acid (H3Pdc): [Cd2(HPdc)1.5Cl(H2O)2] n

Loading next page...
 
/lp/springer_journal/a-three-dimensional-coordination-polymer-based-on-3-5-Rc9xYcluKN
Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S107032841506007X
Publisher site
See Article on Publisher Site

Abstract

The title coordination polymer, [Cd2(HPdc)1.5Cl(H2O)2] n (I) (H3Pdc = 3,5-pyrazoledicarboxylic acid), has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction (CIF file CCDC no. 1037505). Complex I crystallizes in orthorhombic space group Pbcn with a = 10.2631(11), b = 17.1997(18), c = 14.3044(15) Å, V = 2525.0(5) Å3, C15H14Cd4Cl2N6O16, M = 1054.82, ρc = 2.775 g/cm3, μ(MoK α) = 3.627 mm−1, F(000) = 2000, GOOF = 1.067, Z = 4, the final R 1 = 0.0562 and wR 2 = 0.1301 for I > 2σ(I). The Cd(1) ions and HPdc2- ligands connect to form a serial of the 2D corrugated 63 sheets packing parallel along the z axis. Each 63 sheet is connected with the two neighboring sheets by the Cl− and Cd(2) ions to construct the 3D framework of I. The 3D structure can also be rationalized as a 4-connected trinodal (4.5.72.8.9)(4.52.62.7)(4.5.6.73) topological network (the long Schläfli symbol is (4.5.7.7.102)(4.124.5.6.5.7)(4.5.6.7.7.7)) by considering the Cd(1), Cd(2) ions and HPdc2− ligands as 4-connected nodes, the Cl− ions as linkers, respectively.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Jun 3, 2015

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve Freelancer

DeepDyve Pro

Price
FREE
$49/month

$360/year
Save searches from Google Scholar, PubMed
Create lists to organize your research
Export lists, citations
Read DeepDyve articles
Abstract access only
Unlimited access to over
18 million full-text articles
Print
20 pages/month
PDF Discount
20% off