The title coordination polymer, [Cd2(HPdc)1.5Cl(H2O)2] n (I) (H3Pdc = 3,5-pyrazoledicarboxylic acid), has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction (CIF file CCDC no. 1037505). Complex I crystallizes in orthorhombic space group Pbcn with a = 10.2631(11), b = 17.1997(18), c = 14.3044(15) Å, V = 2525.0(5) Å3, C15H14Cd4Cl2N6O16, M = 1054.82, ρc = 2.775 g/cm3, μ(MoK α) = 3.627 mm−1, F(000) = 2000, GOOF = 1.067, Z = 4, the final R 1 = 0.0562 and wR 2 = 0.1301 for I > 2σ(I). The Cd(1) ions and HPdc2- ligands connect to form a serial of the 2D corrugated 63 sheets packing parallel along the z axis. Each 63 sheet is connected with the two neighboring sheets by the Cl− and Cd(2) ions to construct the 3D framework of I. The 3D structure can also be rationalized as a 4-connected trinodal (188.8.131.52.9)(184.108.40.206)(220.127.116.11) topological network (the long Schläfli symbol is (18.104.22.168.102)(22.214.171.124.5.7)(126.96.36.199.7.7)) by considering the Cd(1), Cd(2) ions and HPdc2− ligands as 4-connected nodes, the Cl− ions as linkers, respectively.
Russian Journal of Coordination Chemistry – Springer Journals
Published: Jun 3, 2015
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