A study on one-electron oxidation of phenothiazine derivatives BV piperidine oxoammonium ion in SDS micelle

A study on one-electron oxidation of phenothiazine derivatives BV piperidine oxoammonium ion in... N-Substituted phenothiazines were oxidized by 2,2,6,6-tetramethy-4-acetyloxypiperidine oxoammonium hexachloroantimonate (TAPO) to the corresponding radical cations in sodium dodecyl sulfate (SDS) micellar solution. The radical cations of phenothiazine derivatives were generated and stabilized by the anionic micelle in queous solution. An electron transfer mechanism has been proposed. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

A study on one-electron oxidation of phenothiazine derivatives BV piperidine oxoammonium ion in SDS micelle

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Publisher
Springer Netherlands
Copyright
Copyright © 1998 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856798X00582
Publisher site
See Article on Publisher Site

Abstract

N-Substituted phenothiazines were oxidized by 2,2,6,6-tetramethy-4-acetyloxypiperidine oxoammonium hexachloroantimonate (TAPO) to the corresponding radical cations in sodium dodecyl sulfate (SDS) micellar solution. The radical cations of phenothiazine derivatives were generated and stabilized by the anionic micelle in queous solution. An electron transfer mechanism has been proposed.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 14, 2009

References

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