In this study a novel method for direct synthesis of 2-phenyl heteroaromatic arenes was successfully developed. The title compounds were synthesized by reaction of heteroaromatic compounds with diphenylene iodonium trifluoromethanesulfonate in the presence of 5 mol% Pd(OAc)2 under mild reaction conditions (THF, 60 °C, 24 h). The proposed reaction mechanism was studied by HPLC.
Research on Chemical Intermediates – Springer Journals
Published: Dec 29, 2011
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