Access the full text.
Sign up today, get DeepDyve free for 14 days.
F. Birch (1947)
Finite Elastic Strain of Cubic CrystalsPhysical Review, 71
C. Seagle, D. Heinz, Zhenxian Liu, R. Hemley (2009)
Synchrotron infrared reflectivity measurements of iron at high pressures.Applied optics, 48 3
K. Okazaki, G. Hirth (2016)
Dehydration of lawsonite could directly trigger earthquakes in subducting oceanic crustNature, 530
M. Welch, W. Montgomery, E. Balan, P. Lerch (2012)
Insights into the high-pressure behavior of kaolinite from infrared spectroscopy and quantum-mechanical calculationsPhysics and Chemistry of Minerals, 39
T. Inoue, H. Yurimoto, Y. Kudoh (1995)
Hydrous modified spinel, Mg1.75SiH0.5O4: A new water reservoir in the mantle transition regionGeophysical Research Letters, 22
H. Jung, H. Green, L. Dobrzhinetskaya (2004)
Intermediate-depth earthquake faulting by dehydration embrittlement with negative volume changeNature, 428
S. Poli, M. Schmidt (1995)
H2O transport and release in subduction zones : experimental constraints on basaltic and andesitic systemsJournal of Geophysical Research, 100
P. Wallace (2005)
Volatiles in subduction zone magmas: concentrations and fluxes based on melt inclusion and volcanic gas dataJournal of Volcanology and Geothermal Research, 140
B. Toby (2001)
EXPGUI, a graphical user interface for GSASJournal of Applied Crystallography, 34
S. Shieh, H. Mao, R. Hemley, L. Ming (1998)
Decomposition of phase D in the lower mantle and the fate of dense hydrous silicates in subducting slabsEarth and Planetary Science Letters, 159
Duojun Wang, Li Yi, B. Huang, Chuan-jiang Liu (2015)
High-temperature dehydration of talc: a kinetics study using in situ X-ray powder diffractionPhase Transitions, 88
(1976)
Lithogenous material in marine sediments
M. Kanzaki (2010)
Letter. Crystal structure of a new high-pressure polymorph of topaz-OHAmerican Mineralogist, 95
J. Hancock, J. Sharp (1972)
Method of Comparing Solid‐State Kinetic Data and Its Application to the Decomposition of Kaolinite, Brucite, and BaCO3Journal of the American Ceramic Society, 55
A. Faleiros, T. Rabelo, G. Thim, Maria Oliveira (2000)
Kinetics of phase changeMaterials Research-ibero-american Journal of Materials, 3
Kiminori Sato, T. Katsura, E. Ito (1997)
PHASE RELATIONS OF NATURAL PHLOGOPITE WITH AND WITHOUT ENSTATITE UP TO 8 GPA : IMPLICATION FOR MANTLE METASOMATISMEarth and Planetary Science Letters, 146
H. Kodama (1962)
Identification of Kaolin Minerals in the Presence of Chlorite by X-ray Diffraction and Infrared Absorption SpectraClays and Clay Minerals, 11
P. Fumagalli, L. Stixrude, S. Poli, D. Snyder (2001)
The 10Å phase: a high-pressure expandable sheet silicate stable during subduction of hydrated lithosphereEarth and Planetary Science Letters, 186
W. Dollase (1986)
Correction of intensities for preferred orientation in powder diffractometry: application of the March modelJournal of Applied Crystallography, 19
P. Daniels, B. Wunder (1997)
Al 3 Si 2 O 7 (OH) 3 , phase Pi (formerly piezotite); crystal structure of a synthetic high-pressure silicate rediscoveredEuropean Journal of Mineralogy, 8
B. WuNonn, D. Runrn, O. MronNn, F. Sprrnnr, W. Scnnnvnn (2007)
Synthesis , stability , and properties of AlrSiO 4 ( OH ) r : A fully hydrated analogue of topaz
MD Welch, AR Pawley, SE Ashbrook, HE Mason, BL Phillips (2006)
Si vacancies in the 10-Å phaseAm. Mineral., 91
Yuejian Wang, Jianzhong Zhang, Hongwu Xu, Zhijun Lin, L. Daemen, Yusheng Zhao, Liping Wang (2009)
Thermal equation of state of copper studied by high P-T synchrotron x-ray diffractionApplied Physics Letters, 94
D. Kohlstedt, H. Keppler, D. Rubie (1996)
Solubility of water in the α, β and γ phases of (Mg,Fe)2SiO4Contributions to Mineralogy and Petrology, 123
R. Frost, J. Kloprogge, T. Tran, J. Kristóf (1998)
The effect of pressure on the intercalation of an ordered kaoliniteAmerican Mineralogist, 83
A. Pawley (1994)
The pressure and temperature stability limits of lawsonite: implications for H2O recycling in subduction zonesContributions to Mineralogy and Petrology, 118
P. Keken, B. Hacker, E. Syracuse, G. Abers (2011)
Subduction factory: 4. Depth-dependent flux of H2O from subducting slabs worldwideJournal of Geophysical Research, 116
K. Mibe, T. Fujii, A. Yasuda (1999)
Control of the location of the volcanic front in island arcs by aqueous fluid connectivity in the mantle wedgeNature, 401
C. Johnston, Shan-Li Wang, D. Bish, P. Dera, S. Agnew, J. Kenney (2002)
Novel pressure‐induced phase transformations in hydrous layered materialsGeophysical Research Letters, 29
P. Costanzo, R. Giese, M. Lipsicas (1984)
Static and Dynamic Structure of Water in Hydrated Kaolinites. I. The Static StructureClays and Clay Minerals, 32
F. Simon, G. Glatzel (1929)
Bemerkungen zur SchmelzdruckkurveZeitschrift für anorganische und allgemeine Chemie, 178
E. Ohtani (2005)
Water in the mantleElements, 1
W. ScHuror, Universitiit Bayreuth (1995)
Lawsonite: Upper pressure stability and formation of higher density hydrous phases
B. Phillips, H. Mason, S. Guggenheim (2007)
Hydrogen bonded silanols in the 10 Å phase: Evidence from NMR spectroscopyAmerican Mineralogist, 92
Á. Iglesia (1993)
Pressure induced disorder in kaoliniteClay Minerals, 28
S. You, D. Kunz, Matthias Stöter, H. Kalo, B. Putz, J. Breu, A. Talyzin (2013)
Pressure-induced water insertion in synthetic clays.Angewandte Chemie, 52 14
M. Avrami (1940)
Kinetics of Phase Change 2, 8
T. Tsujimori, V. Sisson, J. Liou, G. Harlow, S. Sorensen (2006)
Petrologic characterization of Guatemalan lawsonite eclogite: Eclogitization of subducted oceanic crust in a cold subduction zone, 403
M Kanzaki (2010)
Crystal structure of a new high-pressure polymorph of topaz-OHAm. Mineral., 95
T. Dixon, J. Moore (2007)
The Seismogenic Zone of Subduction Thrust Faults
S. Karato, M. Paterson, J. Fitzgerald (1986)
Rheology of synthetic olivine aggregates: Influence of grain size and waterJournal of Geophysical Research, 91
(1986)
GSAS—General Structure Analysis System
Donghoon Seoung, Yongmoon Lee, C. Kao, T. Vogt, Yongjae Lee (2013)
Super-hydrated zeolites: pressure-induced hydration in natrolites.Chemistry, 19 33
M. Welch, M. Welch, A. Pawley, S. Ashbrook, Harris Mason, Brian Phillips (2006)
Letter. Si vacancies in the 10-Å phaseAmerican Mineralogist, 91
llen Syracusea, Peter Kekenb, Geoffrey Abersc (2010)
he global range of subduction zone thermal models
A. Pawley, M. Welch, A. Lennie, Raymond Jones (2010)
Volume behavior of the 10 Å phase at high pressures and temperatures, with implications for H2O contentAmerican Mineralogist, 95
D. Comboni, P. Lotti, G. Gatta, M. Merlini, H. Liermann, D. Frost (2018)
Pargasite at high pressure and temperaturePhysics and Chemistry of Minerals, 45
Yongjae Lee, Thomas Vogt, J. Hriljac (2004)
Pressure-induced migration of zeolitic water in laumontitePhysics and Chemistry of Minerals, 31
C. Raleigh, M. Paterson (1965)
Experimental deformation of serpentinite and its tectonic implicationsJournal of Geophysical Research, 70
J. Bigham (1995)
Clay Mineralogy: Spectroscopic and Chemical Determinative MethodsJournal of Environmental Quality, 24
E. Ohtani (2015)
Hydrous minerals and the storage of water in the deep mantleChemical Geology, 418
A. Friedrich, D. Wilson, E. Haussühl, B. Winkler, W. Morgenroth, W. Morgenroth, K. Refson, V. Milman (2007)
High-pressure properties of diaspore, AlO(OH)Physics and Chemistry of Minerals, 34
A. Sano, E. Ohtani, T. Kubo, K. Funakoshi (2004)
In situ X-ray observation of decomposition of hydrous aluminum silicate AlSiO3OH and aluminum oxide hydroxide d-AlOOH at high pressure and temperatureJournal of Physics and Chemistry of Solids, 65
B. Wunder, D. Rubie, C. Ross, O. Medenbach, F. Seifert, W. Schreyer (1993)
Synthesis, stability, and properties of Al 2 SiO 4 (OH) 2 ; a fully dehydrated analogue of topazAmerican Mineralogist, 78
M. Wilson (1994)
Clay mineralogy : spectroscopic and chemical determinative methods
C. White, A. Ruiz-Salvador, D. Lewis (2004)
Pressure-induced hydration effects in the zeolite laumontite.Angewandte Chemie, 43 4
J. Smyth (1987)
beta -Mg 2 SiO 4 ; a potential host for water in the mantle?American Mineralogist, 72
H. Liermann, Z. Konôpková, Wolfgang Morgenroth, Konstantin Glazyrin, Jozef Bednarcik, Emma McBride, Sylvain Petitgirard, J. Delitz, M. Wendt, Y. Bican, A. Ehnes, I. Schwark, André Rothkirch, M. Tischer, J. Heuer, H. Schulte-schrepping, T. Kracht, H. Franz (2015)
The Extreme Conditions Beamline P02.2 and the Extreme Conditions Science Infrastructure at PETRA IIIJournal of Synchrotron Radiation, 22
B. Schmandt, S. Jacobsen, T. Becker, Zhenxian Liu, K. Dueker (2014)
Dehydration melting at the top of the lower mantleScience, 344
巽 好幸, S. Eggins (1995)
Subduction zone magmatism
H. Mao, J. Xu, P. Bell (1986)
Calibration of the ruby pressure gauge to 800 kbar under quasi‐hydrostatic conditionsJournal of Geophysical Research, 91
D. Bish, R. Dreele (1989)
Rietveld Refinement of Non-Hydrogen Atomic Positions in KaoliniteClays and Clay Minerals, 37
M. Avrami (1939)
Kinetics of Phase Change. I General TheoryJournal of Chemical Physics, 7
K. Hattori, S. Guillot (2003)
Volcanic fronts form as a consequence of serpentinite dehydration in the forearc mantle wedgeGeology, 31
Donghoon Seoung, Yongmoon Lee, C. Kao, T. Vogt, Yongjae Lee (2015)
Two-Step Pressure-Induced Superhydration in Small Pore Natrolite with Divalent Extra-Framework CationsChemistry of Materials, 27
P. Ulmer, V. Trommsdorff (1995)
Serpentine Stability to Mantle Depths and Subduction-Related MagmatismScience, 268
H. Iwamori (1998)
Transportation of H2O and melting in subduction zonesEarth and Planetary Science Letters, 160
P. Thompson, D. Cox, J. Hastings (1987)
Rietveld refinement of Debye–Scherrer synchrotron X‐ray data from Al2O3Journal of Applied Crystallography, 20
Water is the most abundant volatile component in the Earth. It continuously enters the mantle through subduction zones, where it reduces the melting temperature of rocks to generate magmas. The dehydration process in subduction zones, which determines whether water is released from the slab or transported into the deeper mantle, is an essential component of the deep water cycle. Here we use in situ and time-resolved high-pressure/high-temperature synchrotron X-ray diffraction and infrared spectra to characterize the structural and chemical changes of the clay mineral kaolinite. At conditions corresponding to a depth of about 75 km in a cold subducting slab (2.7 GPa and 200 °C), and in the presence of water, we observe the pressure-induced insertion of water into kaolinite. This super-hydrated phase has a unit cell volume that is about 31% larger, a density that is about 8.4% lower than the original kaolinite and, with 29 wt% H2O, the highest water content of any known aluminosilicate mineral in the Earth. As pressure and temperature approach 19 GPa and about 800 °C, we observe the sequential breakdown of super-hydrated kaolinite. The formation and subsequent breakdown of super-hydrated kaolinite in cold slabs subducted below 200 km leads to the release of water that may affect seismicity and help fuel arc volcanism at the surface.
Nature Geoscience – Springer Journals
Published: Nov 20, 2017
Access the full text.
Sign up today, get DeepDyve free for 14 days.