A novel three-dimensional cobalt(II)-radical complex Co(NITmPy)2[N(CN)2]2: Structure and magnetic properties

A novel three-dimensional cobalt(II)-radical complex Co(NITmPy)2[N(CN)2]2: Structure and magnetic... A novel three-dimensional cobalt(II)-radical complex {Co(NITmPy)2[N(CN)2]2}n (NITmPy = 2-(3′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) is prepared and characterized by X-ray crystallography. The complex crystallizes in the monoclinic system, space group P21/c, with unit cell parameters a = 12.5775(5) Å, b = 10.9340(5) Å, c = 11.6134(5) Å, β = 108.1320(10)°; V = 1517.79(11) Å3, ρcalcd = 1.443 g/cm3, and Z = 2 for R 1 = 0.0463. In the complex, each cobalt ion is six-coordinate with four nitrogen atoms from four N(CN) 2 t- ligands and two nitrogen atoms of pyridyl groups, and the [Co(NITmPy)2]2+ units are linked by N(CN) 2 t- μ-bridging ligands to form a three-dimensional structure. The variable-temperature magnetic susceptibility data show that the complex exhibits weak antiferromagnetic interactions. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

A novel three-dimensional cobalt(II)-radical complex Co(NITmPy)2[N(CN)2]2: Structure and magnetic properties

Loading next page...
 
/lp/springer_journal/a-novel-three-dimensional-cobalt-ii-radical-complex-co-nitmpy-2-n-cn-2-pfCUArTXyR
Publisher
Nauka/Interperiodica
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328406040051
Publisher site
See Article on Publisher Site

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

Monthly Plan

  • Read unlimited articles
  • Personalized recommendations
  • No expiration
  • Print 20 pages per month
  • 20% off on PDF purchases
  • Organize your research
  • Get updates on your journals and topic searches

$49/month

Start Free Trial

14-day Free Trial

Best Deal — 39% off

Annual Plan

  • All the features of the Professional Plan, but for 39% off!
  • Billed annually
  • No expiration
  • For the normal price of 10 articles elsewhere, you get one full year of unlimited access to articles.

$588

$360/year

billed annually
Start Free Trial

14-day Free Trial