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A novel Mn(II) complex with 3-(2,5-dicarboxyl)-5-carboxylpyridine: Synthesis, crystal structure, and interaction with DNA

A novel Mn(II) complex with 3-(2,5-dicarboxyl)-5-carboxylpyridine: Synthesis, crystal structure,... A novel Mn coordination polymer, {[Mn2(L)6] · 2H2O} n , has been synthesized by the reaction of C4H6MnO4 · 4H2O (manganese acetate) with 3-(2,5-dicarboxyl)-5-carboxylpyridine (L). Elemental analysis, IR spectra, thermal analyses, and X-ray single crystal diffraction (CIF file CCDC no. 1061752) were carried out to determine the composition and crystal structure of the complex. The polymer was characterized by UV spectrum, fluorescence spectrum showing that the complex has the ability of interaction with DNA, Gel electrophoresis assay demonstrated the ability of the complex to cleave the HL-60 DNA (HL-60 DNA, which was extracted by ourselves). Further more, the apoptotic test indicates that the complex has an apoptotic effect on JEKO. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

A novel Mn(II) complex with 3-(2,5-dicarboxyl)-5-carboxylpyridine: Synthesis, crystal structure, and interaction with DNA

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References (21)

Publisher
Springer Journals
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
DOI
10.1134/S107032841509002X
Publisher site
See Article on Publisher Site

Abstract

A novel Mn coordination polymer, {[Mn2(L)6] · 2H2O} n , has been synthesized by the reaction of C4H6MnO4 · 4H2O (manganese acetate) with 3-(2,5-dicarboxyl)-5-carboxylpyridine (L). Elemental analysis, IR spectra, thermal analyses, and X-ray single crystal diffraction (CIF file CCDC no. 1061752) were carried out to determine the composition and crystal structure of the complex. The polymer was characterized by UV spectrum, fluorescence spectrum showing that the complex has the ability of interaction with DNA, Gel electrophoresis assay demonstrated the ability of the complex to cleave the HL-60 DNA (HL-60 DNA, which was extracted by ourselves). Further more, the apoptotic test indicates that the complex has an apoptotic effect on JEKO.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Sep 2, 2015

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