A novel coordination polymer [Zn(Bmb)0.5(H2O)2(Tba)] n (I) (Bmb = (1,4-bis(2-methylbenzimidazol-1-yl)butane, H2Tba = 5-tert-butyl-1,3-benzene dicarboxylic acid) has been hydrothermally synthesized and fully characterized by IR, fluorescence spectrum, single crystal and powder X-ray diffraction techniques (CIF file CCDC no. 992083). Crystal structure revealed that the title polymer crystallized in monoclinic, space group C2/c, a = 22.824(5), b = 10.742(2), c = 19.156(4) Å, β = 102.37(3)°, Z = 8. A ladder-like chain is found in polymer I, which is expended to a 3D supramolecular structure through hydrogen bonding and π⋯π interactions.
Russian Journal of Coordination Chemistry – Springer Journals
Published: Jan 7, 2015
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