A Novel Coordinated Polymer [Cu(En)2][(PzTp)Fe(CN)3]2: Synthesis, Crystal Structure, and Inhibiting Left Atrial Myxoma Cell Activity in vitro

A Novel Coordinated Polymer [Cu(En)2][(PzTp)Fe(CN)3]2: Synthesis, Crystal Structure, and... A new cyanide-bridged neutral centrosymmetric cluster [Cu(En)2][(PzTp)Fe(CN)3]2 (I), where En = ethylenediamine, PzTp = tetra(pyrazol-1-yl)borate) was synthesized by a programmed self-assembly of preformed building blocks. Characterization with single crystal X-ray diffraction (CIF file CCDC no. 1555334) showed that the Cu2+ center was located in a large distorted octahedral environment due to the obvious Jahn–Teller effect, which was demonstrated by continuous shape measures with the SHAPE program. Furthermore, no coordinated or free solvent molecules existed in the clusters, showing good roomtemperature stability. In addition, in vitro anticancer activity of compound I on three human cancer cells (SKOV3, A2780, and OVCAR) was further determined. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

A Novel Coordinated Polymer [Cu(En)2][(PzTp)Fe(CN)3]2: Synthesis, Crystal Structure, and Inhibiting Left Atrial Myxoma Cell Activity in vitro

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Publisher
Pleiades Publishing
Copyright
Copyright © 2018 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328418030089
Publisher site
See Article on Publisher Site

Abstract

A new cyanide-bridged neutral centrosymmetric cluster [Cu(En)2][(PzTp)Fe(CN)3]2 (I), where En = ethylenediamine, PzTp = tetra(pyrazol-1-yl)borate) was synthesized by a programmed self-assembly of preformed building blocks. Characterization with single crystal X-ray diffraction (CIF file CCDC no. 1555334) showed that the Cu2+ center was located in a large distorted octahedral environment due to the obvious Jahn–Teller effect, which was demonstrated by continuous shape measures with the SHAPE program. Furthermore, no coordinated or free solvent molecules existed in the clusters, showing good roomtemperature stability. In addition, in vitro anticancer activity of compound I on three human cancer cells (SKOV3, A2780, and OVCAR) was further determined.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Mar 13, 2018

References

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