A hetero trinuclear manganese(III)-iron(II) complex derived from N,N′-bis(5-chlorosalicylidene)-1,2-diaminoethane: Synthesis, crystal structure, and antimicrobial activity

A hetero trinuclear manganese(III)-iron(II) complex derived from... A new hetero trinuclear manganese(III)-iron(II) complex, [Mn(ClSalen)(H2O)]2[Fe(CN)5(NO)] · CH3OH · H2O, where ClSalen is the dianionic form of N,N′-bis(5-chlorosalicylidene)-1,2-diaminoethane, has been prepared and characterized by elemental analyses, IR, and single crystal X-ray crystallographic determination (CIF file CCDC no. 1024666). The crystal of the complex is orthorhombic: space group Pca21, a = 27.784(2), b = 10.8876(6), c = 15.1755(8) Å, V = 4590.5(4) Å3, Z = 2, R 1 = 0.0596, wR 2 = 0.1406. The bis-Schiff base ligand coordinates to the Mn atom through two phenolate O and two imine N atoms. Each Mn atom in the complex is in octahedral coordination, with the equatorial donor atoms come from the Schiff base ligand, and with the axial donor atoms come from a water O atom and a cyanide N atom. The effects of the complex on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans were studied. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

A hetero trinuclear manganese(III)-iron(II) complex derived from N,N′-bis(5-chlorosalicylidene)-1,2-diaminoethane: Synthesis, crystal structure, and antimicrobial activity

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415080011
Publisher site
See Article on Publisher Site

Abstract

A new hetero trinuclear manganese(III)-iron(II) complex, [Mn(ClSalen)(H2O)]2[Fe(CN)5(NO)] · CH3OH · H2O, where ClSalen is the dianionic form of N,N′-bis(5-chlorosalicylidene)-1,2-diaminoethane, has been prepared and characterized by elemental analyses, IR, and single crystal X-ray crystallographic determination (CIF file CCDC no. 1024666). The crystal of the complex is orthorhombic: space group Pca21, a = 27.784(2), b = 10.8876(6), c = 15.1755(8) Å, V = 4590.5(4) Å3, Z = 2, R 1 = 0.0596, wR 2 = 0.1406. The bis-Schiff base ligand coordinates to the Mn atom through two phenolate O and two imine N atoms. Each Mn atom in the complex is in octahedral coordination, with the equatorial donor atoms come from the Schiff base ligand, and with the axial donor atoms come from a water O atom and a cyanide N atom. The effects of the complex on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans were studied.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Aug 1, 2015

References

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