A 1H NMR study of radical copolymerization of N-vinylsuccinimide with n-butyl acrylate in dimethyl sulfoxide

A 1H NMR study of radical copolymerization of N-vinylsuccinimide with n-butyl acrylate in... Kinetic features of radical copolymerization of N-vinylsuccinimide with n-butyl acrylate in dimethyl sulfoxide were studied by 1H NMR spectroscopy. The dependences of the running concentrations of the monomers and of the “instant” and overall compositions of the copolymers on the reaction time were determined. The limiting conversions were established for correct analysis of the kinetic features of copolymerization at essentially different relative activities of the monomers. The copolymerization constants and the probability of alternation of the units in the copolymer chains were calculated. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

A 1H NMR study of radical copolymerization of N-vinylsuccinimide with n-butyl acrylate in dimethyl sulfoxide

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2007 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427207100217
Publisher site
See Article on Publisher Site

Abstract

Kinetic features of radical copolymerization of N-vinylsuccinimide with n-butyl acrylate in dimethyl sulfoxide were studied by 1H NMR spectroscopy. The dependences of the running concentrations of the monomers and of the “instant” and overall compositions of the copolymers on the reaction time were determined. The limiting conversions were established for correct analysis of the kinetic features of copolymerization at essentially different relative activities of the monomers. The copolymerization constants and the probability of alternation of the units in the copolymer chains were calculated.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Nov 24, 2007

References

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