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Zn-K EXAFS investigations on ZnS/ZnO containing vitrified ashes from municipal incinerator facilities

Zn-K EXAFS investigations on ZnS/ZnO containing vitrified ashes from municipal incinerator... Zn-K transmission EXAFS measurements were performed on vitrified ashes from municipal waste incinerator facilities, which contain low amounts of Zn (up to 3 wt%) and sulphur (up to 0.5 wt%) in a ZnS phase. From the Fourier transform it can be concluded that the zinc ions are fourfold co-ordinated by oxygen or sulphur ions. The amount of zinc ions of sulphur environment, e.g. the concentration of ZnS, was determined by Fourier filtering and subsequent parameter fitting. A quantitative analysis of low ZnS concentrations up to 1 wt% has been performed for samples with a molar ratio Zn/S < 5. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Materials Science Springer Journals

Zn-K EXAFS investigations on ZnS/ZnO containing vitrified ashes from municipal incinerator facilities

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References (3)

Publisher
Springer Journals
Copyright
Copyright © 2001 by Kluwer Academic Publishers
Subject
Materials Science; Materials Science, general; Characterization and Evaluation of Materials; Polymer Sciences; Continuum Mechanics and Mechanics of Materials; Crystallography and Scattering Methods; Classical Mechanics
ISSN
0022-2461
eISSN
1573-4803
DOI
10.1023/A:1011802202743
Publisher site
See Article on Publisher Site

Abstract

Zn-K transmission EXAFS measurements were performed on vitrified ashes from municipal waste incinerator facilities, which contain low amounts of Zn (up to 3 wt%) and sulphur (up to 0.5 wt%) in a ZnS phase. From the Fourier transform it can be concluded that the zinc ions are fourfold co-ordinated by oxygen or sulphur ions. The amount of zinc ions of sulphur environment, e.g. the concentration of ZnS, was determined by Fourier filtering and subsequent parameter fitting. A quantitative analysis of low ZnS concentrations up to 1 wt% has been performed for samples with a molar ratio Zn/S < 5.

Journal

Journal of Materials ScienceSpringer Journals

Published: Oct 17, 2004

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